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Biodegradable lactone copolymers. I. Characterization and mechanical behavior of ?-caprolactone and lactide copolymers
Abstract
Various homopolymers, copolymers, and terpolymers based on 2-ethylhexyl acrylate (2-EHA), n-butyl methacrylate (nBMA), and acrylic acid (AA) were synthesized using the well-known free-radical polymerization technique. The polymers were analyzed by 1HNMR and IR spectroscopy to identify and confirm the presence of the monomers in the copolymer and also to check the absence of monomer impurities. A water-vapor transmission rate (WVTR) study of the synthesized adhesives coated on nonwoven polyester fabric was undertaken using the desiccant method. The water-vapor permeability of the various copolymers changed with the change in monomer concentration. The higher the AA content in the copolymer, the higher was the permeability. The trend shown by various copolymers and terpolymers of 2-EHA with respect to their WVTR is 2-EHA-co-AA > 2-EHA-co-nBMA > 2-EHA-co-AA-co-nBMA. © 1996 John Wiley & Sons, Inc.
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“PLCL copolymers have been shown to degrade faster than either homopolymer [46]”
From Tuning structural relaxations, mechanical properties, and degradation timescale of PLLA during hydrolytic degradation by blending with PLCL-PEG (2019) · cites this paper as [46]
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“Although these systems have been previously evaluated 30 -35 and morphological studies have been previously performed by SAXS, 24,27,28 a detailed study of the crystallization kinetics and morphology of both blocks, and their dependence with composition in a wide range has not been reported, as far as we are aware.”
From Crystallization Kinetics and Morphology of Biodegradable Double Crystalline PLLA- b -PCL Diblock Copolymers (2010) · cites this paper as [35]
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“However, many authors observed that it exists a period, especially for amorphous PLA, in the earlier stages of degradation, for which Young's modulus and tensile strength remain constant before decreasing (Tsuji, 2002; Karjalainen et al., 1996; Leroy et al., 2013).”
From Mechanical behaviour׳s evolution of a PLA-b-PEG-b-PLA triblock copolymer during hydrolytic degradation (2016) · cites this paper as Karjalainen et al., 1996
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- Authors
- Hiljanen-Vainio, M., Karjalainen, T., & Sepp�l�, J.
- Venue
- Journal of Applied Polymer Science
- Published
- 1996
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- Hiljanen-Vainio, M., Karjalainen, T., & Sepp�l�, J. (1996). Biodegradable lactone copolymers. I. Characterization and mechanical behavior of ?-caprolactone and lactide copolymers. Journal of Applied Polymer Science. https://doi.org/10.1002/(sici)1097-4628(19960222)59%3A8
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