Proton-conducting polymers with reduced methanol permeation

Walker, M., Baumg�rtner, K.-M., Kaiser, M., Kerres, J., Ullrich, A., R�uchle, E.·1999·Journal of Applied Polymer Science

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Crossref · 10.1002/(sici)1097-4628(19991003)74:1<67::aid-app7>3.0.co;2-2

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  • Proton transfer between sulfonic acid sites and polymeric basic moieties in acid-base membrane blends leads to cross-links that increase osmotic stability (lower solvent swelling) and reduce membrane brittleness upon drying, compared to uncross-linked or covalently crosslinked sulfonic acid polymers.

    “Proton transfer ͑partial or complete͒ between sulfonic acid sites and polymeric basic moieties in the blend lead to the formation of cross-links which increased the osmotic stability ͑lower solvent swelling͒ of the resultant membrane and also reduced membrane brittleness upon drying, as compared to uncross-linked or covalently crosslinked sulfonic acid polymers.”

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Authors
Walker, M., Baumg�rtner, K.-M., Kaiser, M., Kerres, J., Ullrich, A., & R�uchle, E.
Venue
Journal of Applied Polymer Science
Published
1999

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