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New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization
Abstract
Pronounced surface restructuring leads to the formation of chiral kink sites when a chiral molecular overlayer (2,5,8,11,14,17-hexa-(tert-butyl)decacyclene) is adsorbed onto an extended, flat metal surface (Cu{110}). The process is proposed to happen as a result of the adsorbed molecule inducing chirality in the achiral surface.
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“Since the pioneering work of Hedrick in 2001, 324 the application of organic catalysts to ROP has witnessed significant progress in the last 15 years and this field has grown to the point that it now provides a powerful and, in some cases, better alternative to the use of traditional metal-based catalysts.325,326”
From Catalysis as an Enabling Science for Sustainable Polymers (2018) · cites this paper as [324]
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Metadata
- Authors
- Nederberg, F., Connor, E. F., Möller, M., Glauser, T., & Hedrick, J. L.
- Venue
- Angewandte Chemie International Edition
- Published
- 2001
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- CoChat. (2026). Citation check: New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization. https://app.cochat.ai/papers/10.1002/1521-3773(20010716)40:14
- The paper
- Nederberg, F., Connor, E. F., Möller, M., Glauser, T., & Hedrick, J. L. (2001). New Paradigms for Organic Catalysts: The First Organocatalytic Living Polymerization. Angewandte Chemie International Edition. https://doi.org/10.1002/1521-3773(20010716)40%3A14
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
