Ring opening copolymerization ofɛ-caprolactone,γ-(triethylsilyloxy)-ɛ-caprolactone andγ-ethylene ketal-ɛ-caprolactone: a route to hetero-graft copolyesters
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Catalysts which can only start block copolymerisations with one of the monomers have been reported.
“Catalysts, which can only start block copolymerisations with one of the monomers, have been reported.85,86”
Because Zr complexes usually aggregate (coordination number=6), benzyl alcohol has been added to Zr(O-n-C3H7)4; Mn is then determined by the monomer/alcohol molar ratio, with low polydispersities.
“Because Zr complexes usually aggregate (coordination number=6) [29], benzyl alcohol has been advantageously added to Zr(O-n-C 3 H 7 ) 4 [29,30].Mn is then determined by the monomer/alcohol molar ratio, with low polydispersities.”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [30]
In contrast to aluminum alkoxides, the propagation rate decreased regularly with increasing benzyl alcohol/Zr molar ratio.
“In contrast to aluminum alkoxides, the propagation rate decreased regularly with increasing benzyl alcohol/Zr molar ratio.”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [30]
A series of lactones substituted by bromides, acrylates, protected hydroxyl groups, protected carboxyl groups, and terminal olefins or containing ketones have been synthesized and homo- or co-polymerized.
“Later on, a series of lactones substituted by bromides [103,104], acrylates [105], protected hydroxyl goups [106,107] protected carboxyl groups [108][109][110][111][112][113][114][115] and terminal olefins [116,117] or containing ketones [118] have been synthesized and homo-or co-polymerized.”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [107]
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- Authors
- Stassin, F., Halleux, O., Dubois, P., Detrembleur, C., Lecomte, P., & Jérôme, R.
- Venue
- Macromolecular Symposia
- Published
- 2000
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