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Synthesis of well-defined functionalized polymers and star branched polymers by means of living anionic polymerization using specially designed 1,1-diphenylethylene derivatives
Abstract
This article covers precise syntheses of well-defined chain-end and in-chain functionalized polymers, multi-functionalized polymers with a definite number of functional groups, star-branched and graft polymers by recently developed methodologies using specially designed 1,1-diphenylethylene (DPE) derivatives. The DPE derivatives include various substituted DPE derivatives with functional groups and their derivatives, DPE-functionalized DPE derivatives, and well-defined DPE-functionalized macromonomers. The synthetic utility and importance of these DPE derivatives are described via such polymer syntheses.
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“Because of its superior control over the molecular weight, architecture, composition, and functionality as compared to controlled radical polymerization, almost all well-defined BCPs with complex architectures such as star, comb, graft, dendritic, etc. are achievable via the combination of anionic polymerization and linking chemistry [6,42,43,44,45,46,47].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [44]
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- Authors
- Hirao, A., Hayashi, M., & Haraguchi, N.
- Venue
- Macromolecular Rapid Communications
- Published
- 2000
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- Hirao, A., Hayashi, M., & Haraguchi, N. (2000). Synthesis of well-defined functionalized polymers and star branched polymers by means of living anionic polymerization using specially designed 1,1-diphenylethylene derivatives. Macromolecular Rapid Communications. https://doi.org/10.1002/1521-3927(20001101)21%3A17
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Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
