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Polar and Nonpolar Solvation Dynamics, Ion Diffusion, and Vibrational Relaxation: Role of Biphasic Solvent Response in Chemical Dynamics
Abstract
This chapter contains sections titled: Introduction Progress in the Development of Microscopic Theories Polarization Relaxation in a Dipolar Liquid: Generalized Molecular Hydrodynamic Theory Polar Solvation Dynamics: Microscopic Approach Solvation Dynamics in Water: Polarizability and Solvent Isotope Effects Ionic and Dipolar Solvation Dynamics in Monohydroxy Alcohols Ion Solvation Dynamics in Slow, Viscous Liquids: Role of Solvent Structure and Dynamics Ion Solvation Dynamics in Nonassociated Polar Solvents Origin of the Ultrafast Component in Solvent Response and the Validity of the Continuum Model Ion Solvation Dynamics in Supercritical Water Nonpolar Solvation Dynamics: Role of Binary Interaction in the Ultrafast Response of a Dense Liquid Vibrational Energy Relaxation Vibrational Phase Relaxation in Liquids: Nonclassical Behavior Owing to Bimodal Friction Limiting Ionic Conductivity in Electrolyte Solutions: A Molecular Theory Limiting Ionic Conductivity of Aqueous Electrolyte Solutions: Temperature Dependence and Solvent Isotope Effects Ionic Mobility in Monohydroxy Alcohols Microscopic Derivation of the Hubbard-Onsager Expression of Limiting Ionic Conductivity Dynamics of Solvation in Electrolyte Solutions Dielectric Relaxation and Solvation Dynamics in Organized Assemblies Future Problems
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Citations
Cites
Large local energy fluctuations in water. II. Cooperative motions and fluctuations
Ohmine, I., Tanaka, H., & Wolynes, P. G. (1988) · The Journal of Chemical Physics · doi:10.1063/1.455536 · Cited by 216
Cited by
Biological Water: Femtosecond Dynamics of Macromolecular Hydration
Pal, S. K., Peon, J., Bagchi, B., & Zewail, A. H. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0213506 · Cited by 494
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Metadata
- Authors
- Bagchi, B., & Biswas, R.
- Venue
- Advances in Chemical Physics
- Publisher
- Wiley
- Published
- 1999-01
- Pages
- 207-433
- ISSN
- 0065-2385 (ISSN-L)
- 1934-4791
- OpenAlex
- W2952476509
- Cited by
- 161
- References
- 1
- Type
- other
- Language
- en
- Open access
- closed
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- Bagchi, B., & Biswas, R. (1999). Polar and Nonpolar Solvation Dynamics, Ion Diffusion, and Vibrational Relaxation: Role of Biphasic Solvent Response in Chemical Dynamics. Advances in Chemical Physics. https://doi.org/10.1002/9780470141687.ch4
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