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Cited by 14Advanced Polymer Synthesis and CharacterizationPhotopolymerization techniques and applicationsSynthesis and properties of polymers

Mn2(CO)10‐Visible Light Photomediated, Controlled Radical Polymerization of Main Chain Fluorinated Monomers and Synthesis of Block Copolymers Thereof

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Asandei, Alexandru D., Adebolu, Olumide I., Simpson, Christopher P.·2014·Handbook of Fluoropolymer Science and Technology
DOI 10.1002/9781118850220.ch2
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Abstract

This chapter demonstrates that metal-catalyzed initiation of the polymerization of main chain fluorinated gaseous monomers such as vinylidene fluoride (VDF), can easily be accomplished at 0–100°C, including at rt upto 40°C, directly from a wide variety of alkyl, semifluorinated and perfluoroalkyl halides (Cl, Br, I), using a visible light, Mn2(CO)10 photomediated protocol, carried out in low pressure glass tubes, and which is especially successful in dimethyl carbonate. Fluoropolymers constitute a fundamental class of specialty materials endowed with wide morphological versatility, high thermal, chemical, aging, and weather resistance, as well as low surface energy, dielectric constant, flammability, refractive index, and moisture absorption. Typical VDF laboratory polymerizations are carried out in acetonitrile (ACN) that is a nonsolvent and a weak chain transfer agent (CTA).

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  • One criterion used by 3M Company to screen and select its replacement to PFOA in fluoropolymer production (ADONA) was that the alternative fulfills all requirements for the polymerization process with minor process adjustments.

    “one of the criteria used by 3M Company to screen and select its replacement to PFOA in the production process of fluoropolymers (i.e., ADONA)6 was that the alternative”

    From A Never-Ending Story of Per- and Polyfluoroalkyl Substances (PFASs)? (2017) · cites this paper as [54]

    The Introduction (§2.1) and Solvent Effect (§2.3.2) discuss fluoropolymerization methods and solvent selection, but do not address 3M’s selection of ADONA. Searches for ADONA, PFOA, 3M, and minor process adjustments found no passage supporting the stated criterion. Page numbers were not available in our copy. (LLM, conf=0.74)

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Authors
Asandei, A. D., Adebolu, O. I., & Simpson, C. P.
Affiliations
University of Connecticut (US)
ORCID
Venue
Handbook of Fluoropolymer Science and Technology
Publisher
Wiley
Published
2014-05-02
Pages
21-42
DOI
10.1002/9781118850220.ch2
OpenAlex
W1558656871
Cited by
14
References
0
Citations by year
2025: 1 · 2023: 1 · 2020: 1 · 2019: 3 · 2017: 1 · 2016: 2 · 2015: 4 · 2014: 1
Type
other
Language
en
Open access
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
  • Physical Sciences › Chemistry › Organic Chemistry › Photopolymerization techniques and applications
  • Physical Sciences › Materials Science › Polymers and Plastics › Synthesis and properties of polymers
Keywords
Mn2(CO)10, controlled radical polymerization, vinylidene fluoride, block copolymers, fluorinated polymers, perfluoroalkyl halides, dimethyl carbonate, low-temperature polymerization, chain transfer agent

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