Modern Fluoroorganic Chemistry: Synthesis, Reactivity, Applications

Ag-Mediated Trifluoromethylthiolation of Inert Csp3–H Bond

Zhao, Y., Lin, J., Hang, X., et al. (2018) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.8b02207 · Cited by 36

Fluoroalkylation of Various Nucleophiles with Fluoroalkyl Sulfones through a Single Electron Transfer Process

Xiao, P., Ni, C., Miao, W., et al. (2019) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.9b00419 · Cited by 36

Cu‐Promoted Oxidative Trifluoromethylation of Terminal Alkynes with Difluoromethylene Phosphobetaine

Deng, X., Lin, J., Zheng, J. Z., et al. (2014) · Chinese Journal of Chemistry · doi:10.1002/cjoc.201400427 · Cited by 36

Enantio‐ and Site‐Selective α‐Fluorination of N ‐Acyl 3,5‐Dimethylpyrazoles Catalyzed by Chiral π–Cu II Complexes

Ishihara, K., Nishimura, K., & Yamakawa, K. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202007403 · Cited by 36

Nickel-Catalyzed Exhaustive Hydrodefluorination of Perfluoroalkyl Arenes

Doi, R., Yasuda, M., Kajita, N., Koh, K., & Ogoshi, S. (2023) · Journal of the American Chemical Society · doi:10.1021/jacs.3c03471 · Cited by 38

In situ tunable pillaring of compact and high-density graphite fluoride with pseudocapacitive diamines for supercapacitors with combined predominance in gravimetric and volumetric performances

Zhao, F., Kong, Y., Pan, B., et al. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta09782h · Cited by 36

Copper‐Catalyzed Trifluoromethylthiolation of Di(hetero)aryl‐λ3‐iodanes: Mechanistic Insight and Application to Synthesis of (Hetero)Aryl Trifluoromethyl Sulfides

Saravanan, P., & Anbarasan, P. (2015) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201500606 · Cited by 35

Anti-Selective Aldol Reactions of Pentafluorosulfanylacetic Acid Esters with Aldehydes Mediated by Dicyclohexylchloroborane

Friese, F. W., Dreier, A., Matsnev, A. V., et al. (2016) · Organic Letters · doi:10.1021/acs.orglett.6b00136 · Cited by 35

Highly Efficient Synthesis of Chiral α-CF 3 Amines via Rh-Catalyzed Asymmetric Hydrogenation

Jiang, J., Lu, W., Lv, H., et al. (2015) · Organic Letters · doi:10.1021/acs.orglett.5b00087 · Cited by 35

The Reactivity of Difluorocarbene with Hydroxylamines: Synthesis of Carbamoyl Fluorides

Baars, H., Engel, J., Mertens, L., et al. (2016) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201600308 · Cited by 35

Direct α‐C–H Trifluoromethylselenolation of Carbonyl Compounds

Ghiazza, C., Tlili, A., & Billard, T. (2018) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201800237 · Cited by 35

Photo-induced, Cu-catalyzed three component azidofluoroalkylation of alkenes with CF 3 I and R f I as fluoroalkylation reagents

Liu, H. S., Guo, Q., Chen, C., et al. (2018) · Organic Chemistry Frontiers · doi:10.1039/c8qo00120k · Cited by 35

An eccentric rod-like linear connection of two heterocycles: synthesis of pyridine trans -tetrafluoro-λ 6 -sulfanyl triazoles

Das, P., Niina, K., Hiromura, T., et al. (2018) · Chemical Science · doi:10.1039/c8sc01216d · Cited by 35

Pd‐Catalyzed Transfer of Difluorocarbene for Three Component Cross‐Coupling †

Xu, Z., Zhang, W., Lin, J., et al. (2020) · Chinese Journal of Chemistry · doi:10.1002/cjoc.202000297 · Cited by 35

Chalcogenide-Catalyzed Intermolecular Electrophilic Thio- and Halofunctionalization of gem-Difluoroalkenes: Construction of Diverse Difluoroalkyl Sulfides and Halides

Jiang, Q., Liang, Y., Zhang, Y., et al. (2020) · Organic Letters · doi:10.1021/acs.orglett.0c02784 · Cited by 35

Diels–Alder Reaction in the Synthesis of Fluorinated (Hetero)Aromatic Compounds

Kondratov, I. S., Tolmachova, N. A., & Haufe, G. (2018) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201800327 · Cited by 35

Palladium-catalyzed difluoroalkylative carbonylation of styrenes toward difluoropentanedioates

Bao, Z., Zhang, Y., & Wu, X. (2022) · Chemical Science · doi:10.1039/d2sc02665a · Cited by 34

Difluoromethyl and Chlorofluoromethyl Sulfoximines: Synthesis and Evaluation as Electrophilic Perfluoroalkylating Reagents

Pégot, B., Urban, C., Bourne, A., et al. (2015) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201500201 · Cited by 34

One‐pot synthesis of trifluoromethylated benzimidazolines catalyzed by phosphotungstic acid with a low catalyst loading

Feng, X., Yang, T., He, X., et al. (2018) · Applied Organometallic Chemistry · doi:10.1002/aoc.4314 · Cited by 34

Copper-promoted/copper-catalyzed trifluoromethylselenolation reactions

Ghiazza, C., & Tlili, A. (2020) · Beilstein Journal of Organic Chemistry · doi:10.3762/bjoc.16.30 · Cited by 34

Preparation of 1-Azido-2-Bromo-1,1,2,2-Tetrafluoroethane and Its Use in the Synthesis of N-Fluoroalkylated Nitrogen Heterocycles

Tichý, D., Košťál, V., Motornov, V., et al. (2020) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.0c01610 · Cited by 34

Synthesis, characterization and biological evaluation of cationic hydrazone copper complexes with diverse diimine co-ligands

Chew, S. T., Lo, K. M., Sinniah, S. K., et al. (2014) · RSC Advances · doi:10.1039/c4ra11716f · Cited by 34

Functionalization of Zr-based MOFs with alkyl and perfluoroalkyl groups: the effect on the water sorption behavior

Yu, C., Bourrelly, S., Martineau, C., et al. (2015) · Dalton Transactions · doi:10.1039/c5dt02908b · Cited by 33

First efficient synthesis of SF 5 -substituted pyrrolidines using 1,3-dipolar cycloaddition of azomethine ylides with pentafluorosulfanyl-substituted acrylic esters and amides

Falkowska, E., Tognetti, V., Joubert, L., et al. (2014) · RSC Advances · doi:10.1039/c4ra14075c · Cited by 33

Synthesis of pyridine trans -tetrafluoro-λ 6 -sulfane derivatives via radical addition

Das, P., Takada, M., Tokunaga, E., Saito, N., & Shibata, N. (2017) · Organic Chemistry Frontiers · doi:10.1039/c7qo00994a · Cited by 33

POCl3‐Promoted Trifluoromethylthiolation‐Based Vicinal Bifunctionalization of Indoles with CF3SO2Na

Sun, D., Jiang, X., Jiang, M., et al. (2018) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201800249 · Cited by 33

C−H and C−F Bond Activation Reactions of Fluorinated Propenes at Rhodium: Distinctive Reactivity of the Refrigerant HFO‐1234yf

Talavera, M., von Hahmann, C. N., Müller, R., et al. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201902872 · Cited by 33

Direct Synthesis of Carbamoyl Fluorides by CO 2 Deoxyfluorination

Onida, K., & Tlili, A. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201907354 · Cited by 33

Visible Light‐Induced Radical Iodoperfluoroalkylation of Unactivated Olefins Cooperatively Catalyzed by Enamines and Amines

Yajima, T., Murase, M., & Ofuji, Y. (2020) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201901896 · Cited by 33

Pd-Catalyzed Perfluoroalkylative Aryloxycarbonylation of Alkynes with Formates as CO Surrogates

Gatlik, B., & Chaładaj, W. (2021) · ACS Catalysis · doi:10.1021/acscatal.1c00671 · Cited by 33

Synthesis of 5‐Fluorotriazoles by Silver‐Mediated Fluorination of 5‐Iodotriazoles

Wang, D., Sun, W., & Chu, T. (2015) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201500338 · Cited by 33

Facile difluoromethylation of aliphatic alcohols with an S -(difluoro-methyl)sulfonium salt: reaction, scope and mechanistic study

Liu, G., Li, X., Qin, W., et al. (2019) · Chemical Communications · doi:10.1039/c9cc03487k · Cited by 33

Transition Metal-Catalyzed Arene Trifluoromethylation

Cui-ping, L., Shen, Q., & Liu, D. (2012) · Chinese Journal of Organic Chemistry · doi:10.6023/cjoc1110151 · Cited by 32

A photochemical approach to aromatic extension of the corannulene nucleus

Rajeshkumar, V., & Stuparu, M. C. (2016) · Chemical Communications · doi:10.1039/c6cc04910a · Cited by 32

Chemoselective N-Difluoromethylation of Functionalized Tertiary Amines

Zafrani, Y., Amir, D., Yehezkel, L., Madmon, M., Saphier, S., Karton-Lifshin, N., & Gershonov, E. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.6b01728 · Cited by 33

Superhydrophobic functionalization of cutinase activated poly(lactic acid) surfaces

Ortner, A., Pellis, A., Gamerith, C., Yebra, A. O., Scaini, D., Kaluzna, I. A., Mink, D., Wildeman, S. M. A. D., Acero, E. H., & Guebitz, G. M. (2016) · Green Chemistry · doi:10.1039/c6gc03150a · Cited by 32

A Systematic Assessment of Trifluoromethyl Radical Donor Abilities of Electrophilic Trifluoromethylating Reagents

Li, M., Wang, Y., Xue, X., et al. (2016) · Asian Journal of Organic Chemistry · doi:10.1002/ajoc.201600539 · Cited by 32

Enantioselective Fluorocyclizations Mediated by Amino‐Acid‐Derived Phthalazine

Wang, H.-T., Wang, Y., Liu, S., Mai, Y., Zong, X., Gao, H., Hu, R., Jiang, X., & Yeung, Y. (2019) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201900814 · Cited by 32

Fluorine-induced emission enhancement of tolanes via formation of tight molecular aggregates

Morita, M., Yamada, S., & Konno, T. (2020) · New Journal of Chemistry · doi:10.1039/d0nj01268h · Cited by 32

Synthesis of gem -difluoroalkenes via nickel-catalyzed allylic defluorinative reductive cross-coupling of trifluoromethyl alkenes with epoxides

Lu, X., Jiang, R.-C., Li, J., et al. (2020) · Organic & Biomolecular Chemistry · doi:10.1039/d0ob00535e · Cited by 32

Base-Catalyzed H/D Exchange Reaction of Difluoromethylarenes

Huang, L., Liu, W., Zhao, L., et al. (2021) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.0c02827 · Cited by 32

Stabilization of Lewis Acidic AuF3 as an N‐Heterocyclic Carbene Complex: Preparation and Characterization of [AuF3(SIMes)]

Ellwanger, M. A., Steinhauer, S., Golz, P., et al. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201802952 · Cited by 32

Photocatalyzed [2+1] cyclization of alkenes and silylated trifluorodiazoethanes: facile entry into (difluoromethylene)cyclopropanes

Chen, S., Zhang, Y., Liu, S., et al. (2023) · Science China Chemistry · doi:10.1007/s11426-023-1676-y · Cited by 31

Synthesis of a rhodium( i ) germyl complex: a useful tool for C–H and C–F bond activation reactions

Ahrens, T., Ahrens, M., Braun, T., et al. (2016) · Dalton Transactions · doi:10.1039/c5dt04845a · Cited by 31

Ionic Liquids for Fast and Solvent‐Free Nucleophilic Trifluoromethylthiolation of Alkyl Halides and Alcohols

Anselmi, E., Simon, C., Marrot, J., et al. (2017) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201701222 · Cited by 31

Designs and Strategies for the Halo‐Functionalization of Diazo Compounds

Khanal, H. D., Thombal, R. S., Maezono, S. M. B., et al. (2018) · Advanced Synthesis & Catalysis · doi:10.1002/adsc.201800340 · Cited by 31

Photocatalyzed Intermolecular Aminodifluoromethylphosphonation of Alkenes: Facile Synthesis of α,α‐Difluoro‐γ‐aminophosphonates

Yang, Q., Li, C., Qi, Z., et al. (2018) · Chemistry - A European Journal · doi:10.1002/chem.201803409 · Cited by 31

Ni(0)-Catalyzed Three-Component Coupling Reaction of Tetrafluoroethylene and N-Sulfonyl-Substituted Imines with Silanes via Aza-Nickelacycles

Shirataki, H., Ono, T., Ohashi, M., et al. (2018) · Organic Letters · doi:10.1021/acs.orglett.8b03674 · Cited by 31

Diastereoselective synthesis of CF 3 -oxazinoquinolines in water

Muzalevskiy, V. M., Belyaeva, K. V., Trofimov, B. A., et al. (2019) · Green Chemistry · doi:10.1039/c9gc03044a · Cited by 31

α,β-Disubstituted CF3-Enones as a Trifluoromethyl Building Block: Regioselective Preparation of Totally Substituted 3-CF3-Pyrazoles

Muzalevskiy, V. M., Sizova, Z. A., Panyushkin, V. V., Chertkov, V. A., Khrustalev, V. N., & Nenajdenko, V. G. (2021) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.0c02516 · Cited by 31

Nickel‐Catalyzed Regio‐ and Stereoselective Defluorinative Arylation of gem‐Difluorinated Cyclopropanes

Qi, S., Hua, Y., Pan, L., et al. (2023) · Chinese Journal of Chemistry · doi:10.1002/cjoc.202300579 · Cited by 30

Synthesis of SF5-substituted isoxazolidines using 1,3-dipolar cycloaddition reactions of nitrones with pentafluorosulfanyl acrylic esters and amides

Falkowska, E., Laurent, M. Y., Tognetti, V., et al. (2015) · Tetrahedron · doi:10.1016/j.tet.2015.08.050 · Cited by 30

Cu-Mediated 2,2,2-trifluoroethylation of terminal alkynes using 1,1-dichloro-2,2,2-trifluoroethane (HCFC-123)

Han, E., Sun, Y., Shen, Q., et al. (2015) · Organic Chemistry Frontiers · doi:10.1039/c5qo00210a · Cited by 30

Carbene-Induced Intra- vs Intermolecular Transfer-Fluoromethylation of Aryl Fluoromethylthio Compounds under Rhodium Catalysis

Saidalimu, I., Tokunaga, E., & Shibata, N. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00853 · Cited by 30

Ag-Assisted Fluorination of Unprotected 4,6-Disubstituted 2-Aminopyrimidines with Selectfluor

Wang, C., Cai, J., Zhang, M., et al. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.6b02624 · Cited by 30

Fluorinated Unsymmetrical N,N′‐Diaryl Imidazolium Salts—New Functionalized NHC‐Ligand Precursors

Topchiy, M. A., Zotova, M. A., Masoud, S. M., et al. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201700624 · Cited by 30

Fluoroalkyl Amino Reagents for the Introduction of the Fluoro(trifluoromethoxy)methyl Group onto Arenes and Heterocycles

Schmitt, E., Bouvet, S., Pégot, B., et al. (2017) · Organic Letters · doi:10.1021/acs.orglett.7b02444 · Cited by 30

Fe2O3-Promoted Intermolecular Chlorotrifluoromethylthiolation of Alkenes

Jia, Y., Qin, H., Wang, N., et al. (2018) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.7b03261 · Cited by 30

Electrophilic halogenation of hydrazones of CF 3 -ynones. Regioselective synthesis of 4-halo-substituted 3-CF 3 -pyrazoles

Muzalevskiy, V. M., & Nenajdenko, V. G. (2018) · Organic & Biomolecular Chemistry · doi:10.1039/c8ob02247j · Cited by 30

Determination of pKa values of fluorocompounds in water using 19F NMR

Parman, E., Toom, L., Selberg, S., et al. (2019) · Journal of Physical Organic Chemistry · doi:10.1002/poc.3940 · Cited by 30

The Acidities of Nucleophilic Monofluoromethylation Reagents: An Anomalous α‐Fluorine Effect

Zheng, H., Li, Z., Jing, J., Xue, X., & Cheng, J. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202015614 · Cited by 31

Nickel‐Catalyzed Decarboxylative Difluoroalkylation of α,β‐Unsaturated Carboxylic Acids

Li, G., Wang, T., Fei, F., et al. (2016) · Angewandte Chemie · doi:10.1002/ange.201511321 · Cited by 30

Fluorinated Diluents- A Review

Бабаин, В. А., Alyapyshev, M. Y., Ekberg, C. H., et al. (2023) · Solvent Extraction and Ion Exchange · doi:10.1080/07366299.2023.2188055 · Cited by 30

Enantioconvergent Synthesis of α‐Fluoroalkyl Alcohols Enabled by Photocatalytic Radical Brook Rearrangement

Niu, Y., Jin, C., He, X., et al. (2025) · Angewandte Chemie International Edition · doi:10.1002/anie.202507789 · Cited by 29

anti-Selective aminofluorination of alkenes with amidines mediated by hypervalent iodine( iii ) reagents

Chen, H., Kaga, A., & Chiba, S. (2015) · Organic & Biomolecular Chemistry · doi:10.1039/c5ob01854d · Cited by 29

Aminofluorination of 2-alkynylanilines: a Au-catalyzed entry to fluorinated indoles

Arcadi, A., Pietropaolo, E., Alvino, A., et al. (2014) · Beilstein Journal of Organic Chemistry · doi:10.3762/bjoc.10.42 · Cited by 29

Multigram Scale Syntheses of First and Second Generation of Trifluoromethanesulfenamide Reagents

Glenadel, Q., Alazet, S., Baert, F., et al. (2016) · Organic Process Research & Development · doi:10.1021/acs.oprd.6b00062 · Cited by 29

Pd-Catalyzed Carbonylative Carboperfluoroalkylation of Alkynes. Through-Space 13C–19F Coupling as a Probe for Configuration Assignment of Fluoroalkyl-Substituted Olefins

Domański, S., Staszewska‐Krajewska, O., & Chaładaj, W. (2017) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.7b01236 · Cited by 29

Pd-Catalyzed Mizoroki-Heck Reactions Using Fluorine-Containing Agents as the Cross-Coupling Partners

Yang, J., Zhao, H.-W., He, J., & Zhang, C. (2018) · Catalysts · doi:10.3390/catal8010023 · Cited by 29

CaCl2-Promoted Dehydroxytrifluoromethylselenolation of Alcohols with [Me4N][SeCF3]

Wu, S., Jiang, T.-H., & Zhang, C. (2020) · Organic Letters · doi:10.1021/acs.orglett.0c02109 · Cited by 29

Visible-light induced radical aryldifluoromethylation of N-arylacrylamides by [bis(difluoroacetoxy)iodo]benzene

Lu, K., Lei, L., Wei, Q., et al. (2021) · Tetrahedron Letters · doi:10.1016/j.tetlet.2021.152864 · Cited by 29

Synthesis of Aryl Perfluorocyclopropyl Ethers via [2 + 1] Cyclopropanation Using TMSCF2Br Reagent

Liu, R., & Hu, J. (2022) · Organic Letters · doi:10.1021/acs.orglett.2c00958 · Cited by 30

Difluoromethylarylation of Alkynes from [Bis(difluoroacetoxy)iodo]benzene: Access to CF2H-Containing Dibenzazepines

Wang, L., Zhang, Y., Zhu, T., & Wu, J. (2022) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.2c00584 · Cited by 29

A One-Pot Diazotation–Fluorodediazoniation Reaction and Fluorine Gas for the Production of Fluoronaphthyridines

Abele, S., Schmidt, G., Fleming, M. J., et al. (2014) · Organic Process Research & Development · doi:10.1021/op500100b · Cited by 29

Pd-catalyzed divergent trifluoroethylation and arylation of arylboronic acids by aryl(2,2,2-trifluoroethyl)iodonium triflates

Yang, J., Han, Q., Zhao, C., et al. (2016) · Organic & Biomolecular Chemistry · doi:10.1039/c6ob01384h · Cited by 29

Easy Access to SCF2‐Containing Molecules through a Versatile Reagent

Ismalaj, E., Glenadel, Q., & Billard, T. (2017) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201700103 · Cited by 29

Metal‐Free Visible‐Light‐Mediated Hydrotrifluoromethylation of Unactivated Alkenes and Alkynes in Continuous Flow

Barthelemy, A., Dagousset, G., & Magnier, E. (2019) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201901252 · Cited by 29

Mono-, Di-, and Trifluoroalkyl Substituent Effects on the Torquoselectivities of Cyclobutene and Oxetene Electrocyclic Ring Openings

Honda, K., Lopez, S. A., Houk, K. N., et al. (2015) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.5b01361 · Cited by 28

A direct catalytic ring expansion approach to o-fluoronaphthols and o/p-fluorophenols from indanones and 2-cyclopentenones

Chang, J. M., Song, X., Huang, W., et al. (2015) · Chemical Communications · doi:10.1039/c5cc06825h · Cited by 28

Regio- and Diastereoselective Vinylogous Mannich Addition of 3-Alkenyl-2-oxindoles to α-Fluoroalkyl Aldimines

Qing, F., Liu, Y., Yang, Y., et al. (2014) · Synlett · doi:10.1055/s-0034-1379600 · Cited by 28

Transition‐Metal‐Free Catalytic Hydrodefluorination of Polyfluoroarenes by Concerted Nucleophilic Aromatic Substitution with a Hydrosilicate

Kikushima, K., Grellier, M., Ohashi, M., et al. (2017) · Angewandte Chemie · doi:10.1002/ange.201708003 · Cited by 28

Perfluoroarene Interaction-Controlled Chiral Phosphoric Acid-Catalyzed Enantioselective Michael Addition of Difluoroenoxysilanes to Azadienes: a Combination of Experimental and Theoretical Studies

Li, J., Chen, H., Zhong, R., et al. (2022) · ACS Catalysis · doi:10.1021/acscatal.2c01671 · Cited by 28

Catalytic Cycloisomerization–Fluorination Sequence of N‐Propargyl Amides by Iodoarene/HF⋅Pyridine/Selectfluor Systems

Asari, N., Takemoto, Y., Shinomoto, Y., et al. (2016) · Asian Journal of Organic Chemistry · doi:10.1002/ajoc.201600383 · Cited by 28

Perfluoroalkylation of Alkenes by Frustrated Lewis Pairs

Behrends, I., Bähr, S., & Czekelius, C. (2016) · Chemistry - A European Journal · doi:10.1002/chem.201604414 · Cited by 28

Electrophilic Difluoro(phenylthio)methylation: Generation, Stability, and Reactivity of α-Fluorocarbocations

Betterley, N. M., Surawatanawong, P., Prabpai, S., et al. (2013) · Organic Letters · doi:10.1021/ol402631t · Cited by 28

One-Pot Synthesis of 1-Aryl-3-trifluoromethylpyrazoles Using Nitrile Imines and Mercaptoacetaldehyde As a Surrogate of Acetylene

Świątek, K., Utecht‐Jarzyńska, G., Palusiak, M., et al. (2023) · Organic Letters · doi:10.1021/acs.orglett.3c01437 · Cited by 27

Enantioselective 5-exo-Fluorocyclization of Ene-Oximes

Rouno, T., Niwa, T., Nishibashi, K., et al. (2019) · Molecules · doi:10.3390/molecules24193464 · Cited by 27

Study of a Stable “Trifluoromethoxide Anion Solution” Arising from 2,4‐Dinitro‐Trifluoromethoxybenzene

Bonnefoy, C., Chefdeville, E., Panossian, A., Hanquet, G., Leroux, F. R., Toulgoat, F., & Billard, T. (2021) · Chemistry - A European Journal · doi:10.1002/chem.202102809 · Cited by 29

Synthesis of bioactive fluoropyrrolidines via copper( i )-catalysed asymmetric 1,3-dipolar cycloaddition of azomethine ylides

Xu, X. L., Bao, L., Lu, R., Yang, Z., Yan, D., Wang, C., & Teng, H. (2021) · Chemical Science · doi:10.1039/d1sc04595d · Cited by 27

Novel N(SCF 3 )(CF 3 )-amines: synthesis, scalability and stability

Yang, Y., Saffon‐Merceron, N., Vantourout, J. C., & Tlili, A. (2023) · Chemical Science · doi:10.1039/d2sc06542h · Cited by 27

Electrochemical Difunctionalization of gem -Difluoroalkenes: A Metal-Free Synthesis of α-Difluoro(alkoxyl/azolated) Methylated Ethers

Wen, L., Zhou, N., Zhang, Z., et al. (2023) · Organic Letters · doi:10.1021/acs.orglett.3c01130 · Cited by 27

Multigram Laboratory Scale Synthesis of α-Trifluoromethoxy Carbonyl Compounds

Barbion, J., Pazenok, S., Vors, J., et al. (2014) · Organic Process Research & Development · doi:10.1021/op500118r · Cited by 27

Pd-Catalyzed Boroperfluoroalkylation of Alkynes Opens a Route to One-Pot Reductive Carboperfluoroalkylation of Alkynes with Perfluoroalkyl and Aryl Iodides

Domański, S., Gatlik, B., & Chaładaj, W. (2019) · Organic Letters · doi:10.1021/acs.orglett.9b01618 · Cited by 26

Copper-catalyzed trifluoromethylthiolation-peroxidation of alkenes and allenes

Chen, Y., Ma, Y., Li, L., et al. (2020) · Organic Chemistry Frontiers · doi:10.1039/d0qo00533a · Cited by 26

1,4-Fluoroamination of 1,3-Enynes en Route to Fluorinated Allenes

Zhang, Q., Muhammad, M. T., Chiou, M., et al. (2020) · Organic Letters · doi:10.1021/acs.orglett.0c01953 · Cited by 26

Structure Dependence in Asymmetric Deprotonative Fluorination and Fluorocyclization Reactions of Allylamine Derivatives with Linked Binaphthyl Dicarboxylate Phase-Transfer Catalyst

Niwa, T., Nishibashi, K., Sato, H., Ujiie, K., Yamashita, K., Egami, H., & Hamashima, Y. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c06783 · Cited by 26

Transition-metal-free hydroamination/defluorination/cyclization of perfluoroalkyl alkynes with amidines

Sun, L.-W., Yu, Z.-L., Luo, X.-L., et al. (2021) · Organic Chemistry Frontiers · doi:10.1039/d1qo01439k · Cited by 26

Comparative Analysis of Fluorine‐Directed Glycosylation Selectivity: Interrogating C2 [OH → F] Substitution in d‐ Glucose and d‐ Galactose

Santschi, N., & Gilmour, R. (2015) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201501081 · Cited by 26

Heterogeneous Heterobimetallic Catalysis Enabling Expeditious Access to CF3-Containing vic-Amino Alcohols

Karasawa, T., Kumagai, N., & Shibasaki, M. (2017) · Organic Letters · doi:10.1021/acs.orglett.7b03767 · Cited by 26

Asymmetric Fluorination of Cyclic Tetrasubstituted Alkenes with a Pendant Amide Groups under Dianionic Phase-Transfer Catalysis

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