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Fully Reversible Homogeneous and Heterogeneous Li Storage in RuO2 with High Capacity

Balaya, P., Li, H., Kienle, L., Maier, J.·2003·Advanced Functional Materials

Abstract

In this paper, we report that Li can be stored in RuO 2 with an unusually high coulombic efficiency. The process involves three electrochemical steps: i) formation of a Ru/Li 2 O nanocomposite, ii) formation of a Li‐containing surface film, and iii) interfacial deposition of Li within the Ru/Li 2 O matrix. Corresponding to the storage of 5.6 mole of Li ions per mole of RuO 2, a high capacity of 1130 mAh g–1 is achieved. Furthermore, virtually all inserted Li ions can be extracted, corresponding to a nearly 100 % coulombic efficiency at the first cycle. Achieving a complete reversibility for such a Li storage system through complex heterogeneous solid‐state electrochemical reactions is possible because of the formation of nanoscale Ru/Li 2 O during Li insertion and nano‐RuO 2 during Li extraction, in addition to the favorable transport properties of RuO 2 itself.

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Metadata

Authors
Balaya, P., Li, H., Kienle, L., & Maier, J.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2003-08-05
Volume
13
Issue
8
Pages
621-625
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2151910008
Cited by
605
References
0
FWCI
8.72
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Fully Reversible Homogeneous and Heterogeneous Li Storage in RuO2 with High Capacity. https://app.cochat.ai/papers/10.1002/adfm.200304406
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Balaya, P., Li, H., Kienle, L., & Maier, J. (2003). Fully Reversible Homogeneous and Heterogeneous Li Storage in RuO2 with High Capacity. Advanced Functional Materials. https://doi.org/10.1002/adfm.200304406

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.