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Fully Reversible Homogeneous and Heterogeneous Li Storage in RuO2 with High Capacity
Abstract
In this paper, we report that Li can be stored in RuO 2 with an unusually high coulombic efficiency. The process involves three electrochemical steps: i) formation of a Ru/Li 2 O nanocomposite, ii) formation of a Li‐containing surface film, and iii) interfacial deposition of Li within the Ru/Li 2 O matrix. Corresponding to the storage of 5.6 mole of Li ions per mole of RuO 2, a high capacity of 1130 mAh g–1 is achieved. Furthermore, virtually all inserted Li ions can be extracted, corresponding to a nearly 100 % coulombic efficiency at the first cycle. Achieving a complete reversibility for such a Li storage system through complex heterogeneous solid‐state electrochemical reactions is possible because of the formation of nanoscale Ru/Li 2 O during Li insertion and nano‐RuO 2 during Li extraction, in addition to the favorable transport properties of RuO 2 itself.
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Cited by
Electrolytes and Interphases in Li-Ion Batteries and Beyond
Xu, K. (2014) · Chemical Reviews · doi:10.1021/cr500003w · Cited by 5,566
Metadata
- Authors
- Balaya, P., Li, H., Kienle, L., & Maier, J.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2003-08-05
- Volume
- 13
- Issue
- 8
- Pages
- 621-625
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2151910008
- Cited by
- 605
- References
- 0
- FWCI
- 8.72
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Fully Reversible Homogeneous and Heterogeneous Li Storage in RuO2 with High Capacity. https://app.cochat.ai/papers/10.1002/adfm.200304406
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- Balaya, P., Li, H., Kienle, L., & Maier, J. (2003). Fully Reversible Homogeneous and Heterogeneous Li Storage in RuO2 with High Capacity. Advanced Functional Materials. https://doi.org/10.1002/adfm.200304406
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.