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Electron Transport in a Methanofullerene
Abstract
The current–voltage characteristics of methanofullerene [6,6]‐phenyl C 61‐butyric acid methyl ester (PCBM)‐based devices are investigated as a function of temperature. The occurrence of space–charge limited current enables a direct determination of the electron mobility. At room temperature, an electron mobility of μ e = 2 × 10–7 m 2 V–1 s–1 has been obtained. This electron mobility is more than three orders of magnitude larger than the hole mobility of donor‐type conjugated polymer poly(2‐methoxy‐5‐(3′,7′‐dimethyloctyloxy)‐p‐phenylene vinylene) (OC 1 C 10‐PPV). As a result, the dark current in PCBM/OC 1 C 10‐PPV based devices is completely dominated by electrons. The observed field and temperature‐dependence of the electron mobility of PCBM can be described with a Gaussian disorder model. This provides information about the energetic disorder and average transport‐site separation in PCBM.
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Yang, X., Loos, J., Veenstra, S. C., Verhees, W. J. H., Wienk, M. M., Kroon, J. M., Michels, M. A. J., & Janssen, R. A. J. (2005) · Nano Letters · doi:10.1021/nl048120i · Cited by 1,543
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Metadata
- Authors
- Mihailetchi, V. D., van Duren, J. K. J., Blom, P. W. M., Hummelen, J. C., Janssen, R. A. J., Kroon, J. M., Rispens, M. T., Verhees, W. J. H., & Wienk, M. M.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2003-01-16
- Volume
- 13
- Issue
- 1
- Pages
- 43-46
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W1988244638
- Cited by
- 637
- References
- 0
- FWCI
- 24.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Mihailetchi, V. D., van Duren, J. K. J., Blom, P. W. M., Hummelen, J. C., Janssen, R. A. J., Kroon, J. M., Rispens, M. T., Verhees, W. J. H., & Wienk, M. M. (2003). Electron Transport in a Methanofullerene. Advanced Functional Materials. https://doi.org/10.1002/adfm.200390004
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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