The DOI matches its Crossref record; 20 of the 20 references it cites were found in a registry or an index.
Controlling the Morphology of Nanocrystal–Polymer Composites for Solar Cells
Abstract
We have shown recently that the use of high‐aspect‐ratio inorganic nanorods in conjunction with conjugated polymers is a route to obtaining efficient solar cells processed from solution. Here, we demonstrate that the use of binary solvent mixtures in which one of the components is a ligand for the nanocrystals is effective in controlling the dispersion of nanocrystals in a polymer. By varying the concentration of the solvent mixture, phase separation between the nanocrystal and polymer could be tuned from micrometer scale to nanometer scale. In addition, we can achieve nanocrystal surfaces that are free of surfactant through the use of weak binding ligands that can be removed through heating. When combined, the control of film morphology together with surfactant removal result in nanorod–polymer blend photovoltaic cells with a high external quantum efficiency of 59 % under 0.1 mW cm–2 illumination at 450 nm.
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Hybrid Nanorod-Polymer Solar Cells
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Self-citationShape control of CdSe nanocrystals
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Self-citationFormation of High-Quality CdTe, CdSe, and CdS Nanocrystals Using CdO as Precursor
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2.5% efficient organic plastic solar cells
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Cited by
Hybrid Zinc Oxide Conjugated Polymer Bulk Heterojunction Solar Cells
Beek, W. J. E., Wienk, M. M., Kemerink, M., Yang, X., & Janssen, R. A. J. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp050745x · Cited by 910
Gur, I., Fromer, N. A., Chen, C.-P., Kanaras, A. G., & Alivisatos, A. P. (2007) · Nano Letters · doi:10.1021/nl062660t · Cited by 451
Self-citationDesigner polymer–quantum dot architectures
Tomczak, N., Jańczewski, D., Han, M., & Vancso, G. J. (2009) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2008.11.004 · Cited by 332
On the morphology of polymer‐based photovoltaics
Liu, F., Gu, Y., Jung, J. W., Jo, W. H., & Russell, T. P. (2012) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.23063 · Cited by 323
Yan, J., & Saunders, B. R. (2014) · RSC Adv. · doi:10.1039/c4ra07064j · Cited by 320
Metadata
- Authors
- Huynh, W. U., Dittmer, J. J., Libby, W. C., Whiting, G. L., & Alivisatos, A. P.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2003-01-16
- Volume
- 13
- Issue
- 1
- Pages
- 73-79
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W1967419288
- Cited by
- 450
- References
- 20
- FWCI
- 18.77
- Type
- journal article
- Language
- en
- Open access
- closed
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