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Effects of Solvent Mixtures on the Nanoscale Phase Separation in Polymer Solar Cells
Abstract
The mixed solvent approach has been demonstrated as a promising method to modify nanomorphology in polymer solar cells. This work aims to understand the unique role of the additive in the mixture solvent and how the optimized nanoscale phase separation develops laterally and vertically during the non‐equilibrium spin‐coating process. We found the donor/acceptor components in the active layer can phase separate into an optimum morphology with the additive. Supported by AFM, TEM and XPS results, we proposed a model and identified relevant parameters for the additive such as solubility and vapor pressures. Other additives are discovered to show the ability to improve polymer solar cell performance as well.
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Park, S. H., Roy, A., Beaupré, S., Cho, S., Coates, N., Moon, J. S., Moses, D., Leclerc, M., Lee, K., & Heeger, A. J. (2009) · Nature Photonics · doi:10.1038/nphoton.2009.69 · Cited by 4,073
Transition Metal Oxides for Organic Electronics: Energetics, Device Physics and Applications
Meyer, J., Hamwi, S., Kröger, M., Kowalsky, W., Riedl, T., & Kahn, A. (2012) · Advanced Materials · doi:10.1002/adma.201201630 · Cited by 1,248
Zhao, G., He, Y., & Li, Y. (2010) · Advanced Materials · doi:10.1002/adma.201001339 · Cited by 908
Morphology Control in Organic Solar Cells
Zhao, F., Wang, C., & Zhan, X. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201703147 · Cited by 630
Dang, M. T., Hirsch, L., Wantz, G., & Wuest, J. D. (2013) · Chemical Reviews · doi:10.1021/cr300005u · Cited by 587
Metadata
- Authors
- Yao, Y., Hou, J., Xu, Z., Li, G., & Yang, Y.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2008-06-18
- Volume
- 18
- Issue
- 12
- Pages
- 1783-1789
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2145666004
- Cited by
- 671
- References
- 0
- FWCI
- 46.02
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yao, Y., Hou, J., Xu, Z., Li, G., & Yang, Y. (2008). Effects of Solvent Mixtures on the Nanoscale Phase Separation in Polymer Solar Cells. Advanced Functional Materials. https://doi.org/10.1002/adfm.200701459
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