The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Metal‐Free Click Polymerization: Synthesis and Photonic Properties of Poly(aroyltriazole)s
Abstract
Regioselective 1,3‐dipolar polycycloadditions of tetraphenylethene (TPE)‐containing diazides 1–3 and bis(aroylacetylene) 4 are initiated by simple heating, affording poly(aroyltriazole)s (PATAs) P I–P III with high molecular weights in high yields. The PATAs are completely soluble in common organic solvents and stable at temperatures up to 358 °C. Thanks to their TPE units, the polymers show aggregation‐induced emission and work as explosive sensors with high sensitivity. The PATAs are optically transparent in the whole visible spectral region. Their refractive indexes can be tuned to a great extent (Δ n ≈ 0.08) by simply changing their alkyl spacer lengths. The modified Abbé numbers of the PATAs are very high (up to 273), indicative of very low optical dispersions in the telecommunication‐important wavelength region. UV irradiation through a photomask quenches the light emissions of the polymers, enabling the generation of two‐dimensional fluorescent images without development. The polymers can be readily photo‐crosslinked, yielding three‐dimensional patterns with high resolutions.
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Cites
Tornøe, C. W., Christensen, C., & Meldal, M. (2002) · The Journal of Organic Chemistry · doi:10.1021/jo011148j · Cited by 8,696
Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole
Luo, J., Xie, Z., Lam, J. W. Y., Cheng, L., Tang, B. Z., Chen, H., Qiu, C., Kwok, H. S., Zhan, X., Liu, Y., et al. (2001) · Chemical Communications · doi:10.1039/b105159h · Cited by 8,358
Self-citationCuI‐Catalyzed Alkyne–Azide “Click” Cycloadditions from a Mechanistic and Synthetic Perspective
Bock, V. D., Hiemstra, H., & van Maarseveen, J. H. (2006) · European Journal of Organic Chemistry · doi:10.1002/ejoc.200500483 · Cited by 1,452
Cited by
Aggregation-Induced Emission: Together We Shine, United We Soar!
Mei, J., Leung, N. L. C., Kwok, R. T. K., Lam, J. W. Y., & Tang, B. Z. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00263 · Cited by 8,270
Self-citationFluorescence based explosive detection: from mechanisms to sensory materials
Sun, X., Wang, Y., & Lei, Y. (2015) · Chemical Society Reviews · doi:10.1039/c5cs00496a · Cited by 1,243
Qin, A., Lam, J. W. Y., & Tang, B. Z. (2010) · Chemical Society Reviews · doi:10.1039/b909064a · Cited by 587
Self-citationLuminogenic polymers with aggregation-induced emission characteristics
Qin, A., Lam, J. W. Y., & Tang, B. Z. (2012) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2011.08.002 · Cited by 441
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Metadata
- Authors
- Qin, A., Tang, L., Lam, J. W. Y., Jim, C. K. W., Yu, Y., Zhao, H., Sun, J., & Tang, B. Z.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2009-06-12
- Volume
- 19
- Issue
- 12
- Pages
- 1891-1900
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2013105183
- Cited by
- 172
- References
- 3
- FWCI
- 7.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- Qin, A., Tang, L., Lam, J. W. Y., Jim, C. K. W., Yu, Y., Zhao, H., Sun, J., & Tang, B. Z. (2009). Metal‐Free Click Polymerization: Synthesis and Photonic Properties of Poly(aroyltriazole)s. Advanced Functional Materials. https://doi.org/10.1002/adfm.200801933
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