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Supramolecular Assembly of Perylene Bisimide with β‐Cyclodextrin Grafts as a Solid‐State Fluorescence Sensor for Vapor Detection
Abstract
A nanoscopic supramolecular aggregate is constructed from perylene bisimide‐bridged bis‐(permethyl‐β‐cyclodextrins) 1 via π–π stacking interactions. Its self‐assembly behavior in organic and aqueous solutions is investigated by UV–Vis, fluorescence, and 1 H NMR spectroscopy. Transmission electron microscopy and scanning electron microscopy images show the 1D nanorod aggregation of 1, which is birefringent under crossed polarizer conditions and strongly fluorescent as depicted in the fluorescence microscopy image. X‐ray powder diffraction measurements indicate that 1 forms a well‐ordered crystalline arrangement with a π–π stacking distance of 4.02 Å. Furthermore, the solid‐state fluorescence sensing is explored by utilizing the poly(vinylidene fluoride) membrane‐embedded 1, giving that 1, as a novel vapor detecting material, can probe several kinds of volatile organic compounds and, especially, exhibits high sensitivity to organic amines.
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Cited by
Perylene Bisimide Dye Assemblies as Archetype Functional Supramolecular Materials
Würthner, F., Saha-Möller, C. R., Fimmel, B., Ogi, S., Leowanawat, P., & Schmidt, D. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00188 · Cited by 1,737
Huang, C., Barlow, S., & Marder, S. R. (2011) · The Journal of Organic Chemistry · doi:10.1021/jo2001963 · Cited by 1,112
Chen, S., Slattum, P., Wang, C., & Zang, L. (2015) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00312 · Cited by 578
Tunable solid-state fluorescent materials for supramolecular encryption
Hou, X., Ke, C., Bruns, C. J., McGonigal, P. R., Pettman, R. B., & Stoddart, J. F. (2015) · Nature Communications · doi:10.1038/ncomms7884 · Cited by 434
Liu, K., Kang, Y., Wang, Z., & Zhang, X. (2013) · Advanced Materials · doi:10.1002/adma201302015 · Cited by 337
Metadata
- Authors
- Liu, Y., Wang, K., Guo, D., & Jiang, B.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2009-07-16
- Volume
- 19
- Issue
- 14
- Pages
- 2230-2235
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2078667782
- Cited by
- 212
- References
- 0
- FWCI
- 7.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, Y., Wang, K., Guo, D., & Jiang, B. (2009). Supramolecular Assembly of Perylene Bisimide with β‐Cyclodextrin Grafts as a Solid‐State Fluorescence Sensor for Vapor Detection. Advanced Functional Materials. https://doi.org/10.1002/adfm.200900221
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