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Cited by 652

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Organic D‐A‐π‐A Solar Cell Sensitizers with Improved Stability and Spectral Response

Zhu, Weihong, Wu, Yongzhen, Wang, Shutao, Li, Wenqin, Li, Xin, Chen, Jian, Wang, Zhong‐sheng, Tian, He·2011·Advanced Functional Materials

Abstract

A novel concept “D‐A‐π‐A” organic sensitizer instead of traditional D‐π‐A ones is proposed. Remarkably, the incorporated low bandgap, strong electron‐withdrawing unit of benzothiadiazole shows several favorable characteristics in the areas of light‐harvesting and efficiency: i) optimized energy levels, resulting in a large responsive range of wavelengths into NIR region; ii) a very small blue‐shift in the absorption peak on thin TiO 2 films with respect to that in solution; iii) an improvement in the electron distribution of the donor unit to distinctly increase the photo‐stability of synthetic intermediates and final sensitizers. The stability and spectral response of indoline dye‐based DSSCs are improved by the strong electron‐withdrawing benzothiadizole unit in the conjugation bridge. The incident‐photon‐conversion efficiency of WS‐2 reaches nearly 850 nm with a power conversion efficiency as high as 8.7% in liquid electrolyte and 6.6% in ionic‐liquid electrolyte.

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Metadata

Authors
Zhu, W., Wu, Y., Wang, S., Li, W., Li, X., Chen, J., Wang, Z., & Tian, H.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2010-12-10
Volume
21
Issue
4
Pages
756-763
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2102181432
Cited by
652
References
1
FWCI
23.13
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Organic D‐A‐π‐A Solar Cell Sensitizers with Improved Stability and Spectral Response. https://app.cochat.ai/papers/10.1002/adfm.201001801
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Zhu, W., Wu, Y., Wang, S., Li, W., Li, X., Chen, J., Wang, Z., & Tian, H. (2011). Organic D‐A‐π‐A Solar Cell Sensitizers with Improved Stability and Spectral Response. Advanced Functional Materials. https://doi.org/10.1002/adfm.201001801

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