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Solvent‐Induced Morphology in Polymer‐Based Systems for Organic Photovoltaics

Ruderer, Matthias A., Guo, Shuai, Meier, Robert, Chiang, Hsin‐Yin, Körstgens, Volker, Wiedersich, Johannes, Perlich, Jan, Roth, Stephan V., Müller‐Buschbaum, Peter·2011·Advanced Functional Materials

Abstract

Studies on the influence of four different solvents on the morphology and photovoltaic performance of bulk‐heterojunction films made of poly(3‐hexylthiophene) (P3HT) and [6,6]‐phenyl‐C 61 butyric acid methyl ester (PCBM) via spin‐coating for photovoltaic applications are reported. Solvent‐dependent PCBM cluster formation and P3HT crystallization during thermal annealing are investigated with optical microscopy and grazing‐incidence wide‐angle X‐ray scattering (GIWAXS) and are found to be insufficient to explain the differences in device performance. A combination of atomic force microscopy (AFM), X‐ray reflectivity (XRR), and grazing‐incidence small‐angle X‐ray scattering (GISAXS) investigations results in detailed knowledge of the inner film morphology of P3HT:PCBM films. Vertical and lateral phase separation occurs during spin‐coating and annealing, depending on the solvent used. The findings are summarized in schematics and compared with the IV characteristics. The main influence on the photovoltaic performance arises from the vertical material composition and the existence of lateral phase separation fitting to the exciton diffusion length. Absorption and photoluminescence measurements complement the structural analysis.

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Metadata

Authors
Ruderer, M. A., Guo, S., Meier, R., Chiang, H., Körstgens, V., Wiedersich, J., Perlich, J., Roth, S. V., & Müller‐Buschbaum, P.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2011-07-18
Volume
21
Issue
17
Pages
3382-3391
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2020615682
Cited by
231
References
1
FWCI
17.83
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Solvent‐Induced Morphology in Polymer‐Based Systems for Organic Photovoltaics. https://app.cochat.ai/papers/10.1002/adfm.201100945
The paper
Ruderer, M. A., Guo, S., Meier, R., Chiang, H., Körstgens, V., Wiedersich, J., Perlich, J., Roth, S. V., & Müller‐Buschbaum, P. (2011). Solvent‐Induced Morphology in Polymer‐Based Systems for Organic Photovoltaics. Advanced Functional Materials. https://doi.org/10.1002/adfm.201100945

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