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Dramatic Activity of C3N4/BiPO4 Photocatalyst with Core/Shell Structure Formed by Self‐Assembly
Abstract
Core/shell structured C 3 N 4/BiPO 4 photocatalyst is fabricated via a facile ultrasonic dispersion method. The thickness of the shell may be controlled by tuning the amount of C 3 N 4 in the dispersion, which determines the enhanced level of photocatalytic activity. The optimum photocatalytic activity of C 3 N 4/BiPO 4 at a weight ratio of 4% (C 3 N 4/BiPO 4) under UV irradiation is almost 4.5 times as high as that of reference P25 (TiO 2) and 2.5 times of BiPO 4. More attractively, the dramatic visible light photocatalytic activity is generated due to the C 3 N 4 loaded. The enhancement in performance is demonstrated to be the match of lattice and energy level between the C 3 N 4 and BiPO 4. This match facilitates the separation and transfer of photogenerated electron–hole pairs at the heterojunction interfaces and may be important for other core/shell structured materials. In addition, this method is expected to be extended for other C 3 N 4 loaded materials.
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Environmental applications of semiconductor photocatalysis
Hoffmann, M. R., Martin, S. T., Choi, W., & Bahnemann, D. W. (1995) · Chemical Reviews · doi:10.1021/cr00033a004 · Cited by 18,495
Photocatalysis on TiO2 Surfaces: Principles, Mechanisms, and Selected Results
Linsebigler, A. L., Lu, G., & Yates, J. T. (1995) · Chemical Reviews · doi:10.1021/cr00035a013 · Cited by 11,575
Cited by
Kumar, S., Surendar, T., Baruah, A., & Shanker, V. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta00186e · Cited by 624
Ge, L., Han, C., Xiao, X., & Guo, L. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.04.006 · Cited by 401
Wang, X.-J., Yang, W.-Y., Li, F.-T., Xue, Y.-B., Liu, R.-H., & Hao, Y.-J. (2013) · Industrial & Engineering Chemistry Research · doi:10.1021/ie402820v · Cited by 365
Efficient and stable Nb2O5 modified g-C3N4 photocatalyst for removal of antibiotic pollutant
Hong, Y., Li, C., Zhang, G., Meng, Y., Yin, B., Zhao, Y., & Shi, W. (2016) · Chemical Engineering Journal · doi:10.1016/j.cej.2016.04.092 · Cited by 365
Gu, L., Wang, J., Zou, Z., & Han, X. (2014) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2014.01.021 · Cited by 294
Metadata
- Authors
- Pan, C., Xu, J., Wang, Y., Li, D., & Zhu, Y.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2012-01-30
- Volume
- 22
- Issue
- 7
- Pages
- 1518-1524
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2036400710
- Cited by
- 880
- References
- 2
- FWCI
- 29.64
- Type
- journal article
- Language
- en
- Open access
- closed
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- Pan, C., Xu, J., Wang, Y., Li, D., & Zhu, Y. (2012). Dramatic Activity of C3N4/BiPO4 Photocatalyst with Core/Shell Structure Formed by Self‐Assembly. Advanced Functional Materials. https://doi.org/10.1002/adfm.201102306
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