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Ultrathin Mesoporous NiCo2O4 Nanosheets Supported on Ni Foam as Advanced Electrodes for Supercapacitors
Abstract
A facile two‐step method is developed for large‐scale growth of ultrathin mesoporous nickel cobaltite (NiCo 2 O 4) nanosheets on conductive nickel foam with robust adhesion as a high‐performance electrode for electrochemical capacitors. The synthesis involves the co‐electrodeposition of a bimetallic (Ni, Co) hydroxide precursor on a Ni foam support and subsequent thermal transformation to spinel mesoporous NiCo 2 O 4. The as‐prepared ultrathin NiCo 2 O 4 nanosheets with the thickness of a few nanometers possess many interparticle mesopores with a size range from 2 to 5 nm. The nickel foam supported ultrathin mesoporous NiCo 2 O 4 nanosheets promise fast electron and ion transport, large electroactive surface area, and excellent structural stability. As a result, superior pseudocapacitive performance is achieved with an ultrahigh specific capacitance of 1450 F g−1, even at a very high current density of 20 A g−1, and excellent cycling performance at high rates, suggesting its promising application as an efficient electrode for electrochemical capacitors.
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Citations
Cites
Zhong, J.-H., Wang, A.-L., Li, G.-R., Wang, J.-W., Ou, Y.-N., & Tong, Y.-X. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm15863a · Cited by 510
Cited by
Liang, H., Meng, F., Cabán-Acevedo, M., Li, L., Forticaux, A., Xiu, L., Wang, Z., & Jin, S. (2015) · Nano Letters · doi:10.1021/nl504872s · Cited by 987
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Chodankar, N. R., Ji, S.-H., Han, Y.-K., & Kim, D.-H. (2020) · Nano-Micro Letters · doi:10.1007/s40820-019-0337-2 · Cited by 769
Long, X., Li, G., Wang, Z., Zhu, H., Zhang, T., Xiao, S., Guo, W., & Yang, S. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b07728 · Cited by 657
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Xia, C., Jiang, Q., Zhao, C., Hedhili, M. N., & Alshareef, H. N. (2016) · Advanced Materials · doi:10.1002/adma.201503906 · Cited by 614
Hierarchical NiCo2O4@NiCo2O4Core/Shell Nanoflake Arrays as High-Performance Supercapacitor Materials
Liu, X., Shi, S., Xiong, Q., Li, L., Zhang, Y., Tang, H., Gu, C., Wang, X., & Tu, J. (2013) · ACS Applied Materials & Interfaces · doi:10.1021/am402681m · Cited by 533
Metadata
- Authors
- Yuan, C., Li, J., Hou, L., Zhang, X., Shen, L., & Lou, X. W. (.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2012-06-26
- Volume
- 22
- Issue
- 21
- Pages
- 4592-4597
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W1967513663
- Cited by
- 1,688
- References
- 1
- FWCI
- 48.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yuan, C., Li, J., Hou, L., Zhang, X., Shen, L., & Lou, X. W. (. (2012). Ultrathin Mesoporous NiCo2O4 Nanosheets Supported on Ni Foam as Advanced Electrodes for Supercapacitors. Advanced Functional Materials. https://doi.org/10.1002/adfm.201200994
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