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Size‐Controlled Synthesis of Cu2‐xE (E = S, Se) Nanocrystals with Strong Tunable Near‐Infrared Localized Surface Plasmon Resonance and High Conductivity in Thin Films

Liu, Xin, Wang, Xianliang, Zhou, Bin, Law, Wing‐Cheung, Cartwright, Alexander N., Swihart, Mark T.·2013·Advanced Functional Materials

Abstract

A facile method for preparing highly self‐doped Cu 2‐xE (E = S, Se) nanocrystals (NCs) with controlled size in the range of 2.8–13.5 nm and 7.2–16.5 nm, for Cu 2‐xS and Cu 2‐xSe, respectively, is demonstrated. Strong near‐infrared localized surface plasmon resonance absorption is observed in the NCs, indicating that the as‐prepared particles are heavily p‐doped. The NIR plasmonic absorption is tuned by varying the amount of oleic acid used in synthesis. This effect is attributed to a reduction in the number of free carriers through surface interaction of the deprotonated carboxyl functional group of oleic acid with the NCs. This approach provides a new pathway to control both the size and the cationic deficiency of Cu 2‐xSe and Cu 2‐xS NCs. The high electrical conductivity exhibited by these NPs in metal‐semiconductor‐metal thin film devices shows promise for applications in printable field‐effect transistors and microelectronic devices.

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Metadata

Authors
Liu, X., Wang, X., Zhou, B., Law, W., Cartwright, A. N., & Swihart, M. T.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2012-10-15
Volume
23
Issue
10
Pages
1256-1264
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2049981795
Cited by
290
References
1
FWCI
12.45
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Size‐Controlled Synthesis of Cu2‐xE (E = S, Se) Nanocrystals with Strong Tunable Near‐Infrared Localized Surface Plasmon Resonance and High Conductivity in Thin Films. https://app.cochat.ai/papers/10.1002/adfm.201202061
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Liu, X., Wang, X., Zhou, B., Law, W., Cartwright, A. N., & Swihart, M. T. (2013). Size‐Controlled Synthesis of Cu2‐xE (E = S, Se) Nanocrystals with Strong Tunable Near‐Infrared Localized Surface Plasmon Resonance and High Conductivity in Thin Films. Advanced Functional Materials. https://doi.org/10.1002/adfm.201202061

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