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A Giant Electrocaloric Effect in Nanoscale Antiferroelectric and Ferroelectric Phases Coexisting in a Relaxor Pb0.8Ba0.2ZrO3 Thin Film at Room Temperature

Peng, Biaolin, Fan, Huiqing, Zhang, Qi·2013·Advanced Functional Materials

Abstract

Recently, large electrocaloric effects (ECE) in antiferroelectric sol‐gel PbZr 0.95 Ti 0.05 O 3 thin films and in ferroelectric polymer P(VDF‐TrFE)55/45 thin films were observed near the ferroelectric Curie temperatures of these materials (495 K and 353 K, respectively). Here a giant ECE (Δ T = 45.3 K and Δ S = 46.9 J K−1 kg−1 at 598 kV cm−1) is obtained in relaxor ferroelectric Pb 0.8 Ba 0.2 ZrO 3 (PBZ) thin films fabricated on Pt(111)/TiO x/SiO 2/Si substrates using a sol‐gel method. Nanoscale antiferroelectric (AFE) and ferroelectric (FE) phases coexist at room temperature (290 K) rather than at the Curie temperature (408 K) of the material. The giant ECE in such a system is attributed to the coexistence of AFE and FE phases and a field‐induced nanoscale AFE to FE phase transition. The giant ECE of the thin film makes this a promising material for applications in cooling systems near room temperature.

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Metadata

Authors
Peng, B., Fan, H., & Zhang, Q.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2013-01-20
Volume
23
Issue
23
Pages
2987-2992
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2049177906
Cited by
362
References
10
FWCI
12.43
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A Giant Electrocaloric Effect in Nanoscale Antiferroelectric and Ferroelectric Phases Coexisting in a Relaxor Pb0.8Ba0.2ZrO3 Thin Film at Room Temperature. https://app.cochat.ai/papers/10.1002/adfm.201202525
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Peng, B., Fan, H., & Zhang, Q. (2013). A Giant Electrocaloric Effect in Nanoscale Antiferroelectric and Ferroelectric Phases Coexisting in a Relaxor Pb0.8Ba0.2ZrO3 Thin Film at Room Temperature. Advanced Functional Materials. https://doi.org/10.1002/adfm.201202525

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