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Cited by 285

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Similar or Totally Different: The Control of Conjugation Degree through Minor Structural Modifications, and Deep‐Blue Aggregation‐Induced Emission Luminogens for Non‐Doped OLEDs

Huang, Jing, Sun, Ning, Dong, Yongqiang, Tang, Runli, Lu, Ping, Cai, Ping, Li, Qianqian, Ma, Dongge, Qin, Jingui, Li, Zhen·2013·Advanced Functional Materials

Abstract

Four 4,4′‐bis(1,2,2‐triphenylvinyl)biphenyl (BTPE) derivatives, 4,4′‐bis(1,2,2‐triphenylvinyl)biphenyl, 2,3′‐bis(1,2,2‐triphenylvinyl)biphenyl, 2,4′‐bis(1,2,2‐triphenylvinyl)biphenyl, 3,3′‐bis(1,2,2‐triphenylvinyl)biphenyl and 3,4′‐bis(1,2,2‐triphenylvinyl)biphenyl (o TPE‐m TPE, o TPE‐p TPE, m TPE‐m TPE, and m TPE‐p TPE, respectively), are successfully synthesized and their thermal, optical, and electronic properties fully investigated. By merging two simple tetraphenylethene (TPE) units together through different linking positions, the π‐conjugation length is effectively controlled to ensure the deep‐blue emission. Because of the minor but intelligent structural modification, all the four fluorophores exhibit deep‐blue emissions from 435 to 459 nm with Commission Internationale de l'Eclairage (CIE) chromaticity coordinates of, respectively, (0.16, 0.14), (0.15, 0.11), (0.16, 0.14), and (0.16, 0.16), when fabricated as emitters in organic light‐emitting diodes (OLEDs). This is completely different from BTPE with sky‐blue emission (0.20, 0.36). Thus, these results may provide a novel and versatile approach for the design of deep‐blue aggregation‐induced emission (AIE) luminogens.

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Metadata

Authors
Huang, J., Sun, N., Dong, Y., Tang, R., Lu, P., Cai, P., Li, Q., Ma, D., Qin, J., & Li, Z.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2012-12-04
Volume
23
Issue
18
Pages
2329-2337
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2043683929
Cited by
285
References
2
FWCI
17.09
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Similar or Totally Different: The Control of Conjugation Degree through Minor Structural Modifications, and Deep‐Blue Aggregation‐Induced Emission Luminogens for Non‐Doped OLEDs. https://app.cochat.ai/papers/10.1002/adfm.201202639
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Huang, J., Sun, N., Dong, Y., Tang, R., Lu, P., Cai, P., Li, Q., Ma, D., Qin, J., & Li, Z. (2013). Similar or Totally Different: The Control of Conjugation Degree through Minor Structural Modifications, and Deep‐Blue Aggregation‐Induced Emission Luminogens for Non‐Doped OLEDs. Advanced Functional Materials. https://doi.org/10.1002/adfm.201202639

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