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High CO2/CH4 and C2 Hydrocarbons/CH4 Selectivity in a Chemically Robust Porous Coordination Polymer
Abstract
A new porous coordination polymer, ([La(BTB)H 2 O]·solvent (1⊃guest)), is synthesized. Gas adsorption, ideal adsorbed solution theory (IAST) and breakthrough experiments of it exhibits high CH 4 separation capability toward CO 2 and C2 hydrocarbons at 273 K. In addition, this also shows good water and chemical stability, in particular, it is stable at pH = 14 at 100 °C, which is unprecedented for carboxylate‐based porous coordination polymers. Furthermore, the effective adsorption site for separation is revealed by using an in situ diffuse reflectance IR fourier transform (DRIFT) spectra study.
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Citations
Cited by
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
CO2 Capture and Separations Using MOFs: Computational and Experimental Studies
Yu, J., Xie, L.-H., Li, J.-R., Ma, Y., Seminario, J. M., & Balbuena, P. B. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00626 · Cited by 1,047
Structures of Metal–Organic Frameworks with Rod Secondary Building Units
Schoedel, A., Li, M., Li, D., O’Keeffe, M., & Yaghi, O. M. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00346 · Cited by 909
Metal–Organic Frameworks for Food Safety
Wang, P.-L., Xie, L.-H., Joseph, E. A., Li, J.-R., Su, X.-O., & Zhou, H.-C. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00257 · Cited by 533
Construction and application of base-stable MOFs: a critical review
Wang, K., Li, Y., Xie, L.-H., Li, X., & Li, J.-R. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00891a · Cited by 462
Metadata
- Authors
- Duan, J., Higuchi, M., Horike, S., Foo, M. L., Rao, K. P., Inubushi, Y., Fukushima, T., & Kitagawa, S.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2013-02-26
- Volume
- 23
- Issue
- 28
- Pages
- 3525-3530
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2149915957
- Cited by
- 209
- References
- 0
- FWCI
- 10.84
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: High CO2/CH4 and C2 Hydrocarbons/CH4 Selectivity in a Chemically Robust Porous Coordination Polymer. https://app.cochat.ai/papers/10.1002/adfm.201203288
- The paper
- Duan, J., Higuchi, M., Horike, S., Foo, M. L., Rao, K. P., Inubushi, Y., Fukushima, T., & Kitagawa, S. (2013). High CO2/CH4 and C2 Hydrocarbons/CH4 Selectivity in a Chemically Robust Porous Coordination Polymer. Advanced Functional Materials. https://doi.org/10.1002/adfm.201203288
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