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Carbon‐Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability
Abstract
The lithium sulfur battery system has been studied since the late 1970s and has seen renewed interest in recent years. However, even after three decades of intensive research, prolonged cycling can only be achieved when a large excess of electrolyte and lithium is used. Here, for the first time, a balanced and stable lithium sulfur full cell is demonstrated with silicon–carbon as well as all‐carbon anodes. More than 1000 cycles, a specific capacity up to 1470 mAh g−1 sulfur (720 mAh g−1 cathode), and a high coulombic efficiency of over 99% even with a low amount of electrolyte are achieved. The alternative anodes do not suffer from electrolyte depletion, which is found to be the main cause of cell failure when using metallic lithium anodes.
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Cites
Orsini, F., Du Pasquier, A., Beaudoin, B., Tarascon, J. M., Trentin, M., Langenhuizen, N., De Beer, E., & Notten, P. (1998) · Journal of Power Sources · doi:10.1016/s0378-7753(98)00128-1 · Cited by 310
Cited by
Carbon materials for Li–S batteries: Functional evolution and performance improvement
Liang, J., Sun, Z.-H., Li, F., & Cheng, H.-M. (2016) · Energy Storage Materials · doi:10.1016/j.ensm.2015.09.007 · Cited by 593
From lithium to sodium: Cell chemistry of room temperature sodium–air and sodium–sulfur batteries
Adelhelm, P., Hartmann, P., Bender, C. L., Busche, M., Eufinger, C., & Janek, J. (2015) · Beilstein Journal of Nanotechnology · doi:10.3762/bjnano.6.105 · Cited by 478
Nanowires for Electrochemical Energy Storage
Zhou, G., Xu, L., Hu, G., Mai, L., & Cui, Y. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00326 · Cited by 439
Zhou, W., Xiao, X., Cai, M., & Yang, L. (2014) · Nano Letters · doi:10.1021/nl502238b · Cited by 382
A Revolution in Electrodes: Recent Progress in Rechargeable Lithium–Sulfur Batteries
Fang, X., & Peng, H. (2015) · Small · doi:10.1002/smll.201402354 · Cited by 346
Metadata
- Authors
- Brückner, J., Thieme, S., Böttger‐Hiller, F., Bauer, I., Grossmann, H. T., Strubel, P., Althues, H., Spange, S., & Kaskel, S.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2013-08-27
- Volume
- 24
- Issue
- 9
- Pages
- 1284-1289
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2030352345
- Cited by
- 184
- References
- 1
- FWCI
- 13.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Brückner, J., Thieme, S., Böttger‐Hiller, F., Bauer, I., Grossmann, H. T., Strubel, P., Althues, H., Spange, S., & Kaskel, S. (2014). Carbon‐Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability. Advanced Functional Materials. https://doi.org/10.1002/adfm.201302169
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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