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High‐Performance Hybrid Supercapacitor Enabled by a High‐Rate Si‐based Anode

Yi, Ran, Chen, Shuru, Song, Jiangxuan, Gordin, Mikhail L., Manivannan, Ayyakkannu, Wang, Donghai·2014·Advanced Functional Materials

Abstract

A hybrid supercapacitor constructed of a Si‐based anode and a porous carbon cathode is demonstrated with both high power and energy densities. Boron‐doping is employed to improve the rate capability of the Si‐based anode (B‐Si/SiO 2/C). At a high current density of 6.4 A/g, B‐Si/SiO 2/C delivers a capacity of 685 mAh/g, 2.4 times that of the undoped Si/SiO 2/C. Benefiting from the high rate performance along with low working voltage, high capacity, and good cycling stability of B‐Si/SiO 2/C, the hybrid supercapacitor exhibits a high energy density of 128 Wh/kg at 1229 W/kg. Even when power density increases to the level of a conventional supercapacitor (9704 W/kg), 89 Wh/kg can be obtained, the highest values of any hybrid supercapacitor to date. Long cycling life (capacity retention of 70% after 6000 cycles) and low self‐discharge rate (voltage retention of 82% after 50 hours) are also achieved. This work opens an avenue for development of high‐performance hybrid supercapacitors using high‐performance Si‐based anodes.

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Metadata

Authors
Yi, R., Chen, S., Song, J., Gordin, M. L., Manivannan, A., & Wang, D.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2014-09-22
Volume
24
Issue
47
Pages
7433-7439
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2079808008
Cited by
246
References
1
FWCI
6.73
Type
journal article
Language
en
Open access
closed

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Yi, R., Chen, S., Song, J., Gordin, M. L., Manivannan, A., & Wang, D. (2014). High‐Performance Hybrid Supercapacitor Enabled by a High‐Rate Si‐based Anode. Advanced Functional Materials. https://doi.org/10.1002/adfm.201402398

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