The DOI matches its Crossref record; 57 of the 57 references it cites were found in a registry or an index.
Strongly Anisotropic Thermal Conductivity of Free‐Standing Reduced Graphene Oxide Films Annealed at High Temperature
Open accessAbstract
Thermal conductivity of free‐standing reduced graphene oxide films subjected to a high‐temperature treatment of up to 1000 °C is investigated. It is found that the high‐temperature annealing dramatically increases the in‐plane thermal conductivity, K, of the films from ≈3 to ≈61 W m−1 K−1 at room temperature. The cross‐plane thermal conductivity, K⊥, reveals an interesting opposite trend of decreasing to a very small value of ≈0.09 W m−1 K−1 in the reduced graphene oxide films annealed at 1000 °C. The obtained films demonstrate an exceptionally strong anisotropy of the thermal conductivity, K/K⊥ ≈ 675, which is substantially larger even than in the high‐quality graphite. The electrical resistivity of the annealed films reduces to 1–19 Ω □−1. The observed modifications of the in‐plane and cross‐plane thermal conductivity components resulting in an unusual K/K⊥ anisotropy are explained theoretically. The theoretical analysis suggests that K can reach as high as ≈500 W m−1 K−1 with the increase in the sp 2 domain size and further reduction of the oxygen content. The strongly anisotropic heat conduction properties of these films can be useful for applications in thermal management.
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Cited by
Smith, A. T., LaChance, A. M., Zeng, S., Liu, B., & Sun, L. (2019) · Nano Materials Science · doi:10.1016/j.nanoms.2019.02.004 · Cited by 1,643
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Phonons and thermal transport in graphene and graphene-based materials
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Metadata
- Authors
- Renteria, J. D., Ramirez, S., Malekpour, H., Alonso, B., Centeno, A., Zurutuza, A., Cocemasov, A. I., Nika, D. L., & Balandin, A. A.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2015-06-25
- Volume
- 25
- Issue
- 29
- Pages
- 4664-4672
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W1588065219
- Cited by
- 579
- References
- 57
- FWCI
- 20.52
- Type
- journal article
- Language
- en
- Open access
- gold
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- Renteria, J. D., Ramirez, S., Malekpour, H., Alonso, B., Centeno, A., Zurutuza, A., Cocemasov, A. I., Nika, D. L., & Balandin, A. A. (2015). Strongly Anisotropic Thermal Conductivity of Free‐Standing Reduced Graphene Oxide Films Annealed at High Temperature. Advanced Functional Materials. https://doi.org/10.1002/adfm.201501429
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