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Template‐Based Engineering of Carbon‐Doped Co3O4 Hollow Nanofibers as Anode Materials for Lithium‐Ion Batteries
Abstract
Co 3 O 4 anode materials exhibit poor conductivity and a large volume change, rendering controlling of their nanostructure essential to optimize their lithium storage performance. Carbon‐doped Co 3 O 4 hollow nanofibers (C‐doped Co 3 O 4 HNFs), for the first time are synthesized using bifunctional polymeric nanofibers as template and carbon source. Compared with undoped Co 3 O 4 HNFs and solid Co 3 O 4 NFs, C‐doped Co 3 O 4 HNFs feature a remarkably high specific capacity, excellent cycling stability, and superior rate capacity as anode materials for lithium‐ion batteries. The superior performance of C‐doped Co 3 O 4 HNFs electrodes can be attributed to their structural features, which confer enhanced electron transportation and Li+ ion diffusion due to C‐doping, and tolerance for volume change due to the 1D hollow structure. Density functional theory calculations provide a good explanation of the observed enhanced conductivity in C‐doped Co 3 O 4 HNFs.
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Cited by
Zhang, Y., Ouyang, B., Xu, J., Jia, G., Chen, S., Rawat, R. S., & Fan, H. J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604372 · Cited by 737
Electrospun hollow nanofibers for advanced secondary batteries
Li, L., Peng, S., Lee, J. K. Y., Ji, D., Srinivasan, M., & Ramakrishna, S. (2017) · Nano Energy · doi:10.1016/j.nanoen.2017.06.050 · Cited by 267
Yun, X., Lu, T., Zhou, R., Lu, Z., Li, J., & Zhu, Y. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2021.131328 · Cited by 228
Metadata
- Authors
- Yan, C., Chen, G., Zhou, X., Sun, J., & Lv, C.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2016-02-05
- Volume
- 26
- Issue
- 9
- Pages
- 1428-1436
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2297761676
- Cited by
- 446
- References
- 0
- FWCI
- 36.13
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yan, C., Chen, G., Zhou, X., Sun, J., & Lv, C. (2016). Template‐Based Engineering of Carbon‐Doped Co3O4 Hollow Nanofibers as Anode Materials for Lithium‐Ion Batteries. Advanced Functional Materials. https://doi.org/10.1002/adfm.201504695
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