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10.8% Efficiency Polymer Solar Cells Based on PTB7‐Th and PC71BM via Binary Solvent Additives Treatment

Wan, Qun, Guo, Xia, Wang, Zaiyu, Li, Wanbin, Guo, Bing, Ma, Wei, Zhang, Maojie, Li, Yongfang·2016·Advanced Functional Materials

Abstract

In this work, polymer solar cells are fabricated based on the blend of PTB7‐Th: PC 71 BM by using a mixed solvent additive of 1,8‐diiodooctane and N‐methyl pyrrolidone to optimize the morphology of the blend. A high power conversion efficiency (PCE) of 10.8% has been achieved with a simple conventional device. In order to deeply investigate the influence of the mixed solvent additives on the morphology and device performance, the variations of the molecular packing and bulk morphology of the blend film cast from ortho‐dichlorobenzene with single or binary solvent additives are measured. Although all the blend films exhibit similar domain size and nanoscale phase separation, the blend film processed with mixed solvent additive shows the highest domain purity, resulting in the least bimolecular recombination, relatively high Jsc and FF, and hence enhanced PCE. Therefore, the best photovoltaic performance with the Voc of 0.82 V, Jsc of 19.1 mA cm−2, FF of 69.1%, and PCE of 10.8% are obtained for the device based on the blend with binary solvent additive treatment.

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Metadata

Authors
Wan, Q., Guo, X., Wang, Z., Li, W., Guo, B., Ma, W., Zhang, M., & Li, Y.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2016-07-19
Volume
26
Issue
36
Pages
6635-6640
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2486255115
Cited by
299
References
58
FWCI
28.66
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: 10.8% Efficiency Polymer Solar Cells Based on PTB7‐Th and PC71BM via Binary Solvent Additives Treatment. https://app.cochat.ai/papers/10.1002/adfm.201602181
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Wan, Q., Guo, X., Wang, Z., Li, W., Guo, B., Ma, W., Zhang, M., & Li, Y. (2016). 10.8% Efficiency Polymer Solar Cells Based on PTB7‐Th and PC71BM via Binary Solvent Additives Treatment. Advanced Functional Materials. https://doi.org/10.1002/adfm.201602181

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