The DOI matches its Crossref record; 59 of the 59 references it cites were found in a registry or an index.
MoSe2‐Covered N,P‐Doped Carbon Nanosheets as a Long‐Life and High‐Rate Anode Material for Sodium‐Ion Batteries
Abstract
MoSe 2 grown on N,P‐co‐doped carbon nanosheets is synthesized by a solvothermal reaction followed with a high‐temperature calcination. This composite has an interlayer spacing of MoSe 2 expanded to facilitate sodium‐ion diffusion, MoSe 2 immobilized on carbon nanosheets to improve charge‐transfer kinetics, and N and P incorporated into carbon to enhance its interaction with active species upon cycling. These features greatly improve the electrochemical performance of this composite, as compared to all the controls. It presents a specific capacity of 378 mAh g−1 after 1000 cycles at 0.5 A g−1, corresponding to 87% of the capacity at the second cycle. Ex situ Raman spectra and high‐resolution transmission electron microscopy images confirm that it is element Se, rather than MoSe 2, formed after the charging process. The interaction of the active species with modified carbon is simulated using density functional theory to explain this excellent stability. The superior rate capability, where the capacity at 15 A g−1 equals ≈55% of that at 0.5 A g−1, could be associated with the significant contribution of pseudocapacitance. By pairing with homemade Na 3 V 2(PO 4)3/C, this composite also exhibits excellent performances in full cells.
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Fang, G., Wang, Q., Zhou, J., Lei, Y., Chen, Z., Wang, Z., Pan, A., & Liang, S. (2019) · ACS Nano · doi:10.1021/acsnano.9b00816 · Cited by 507
Heteroatom-doped carbon-based materials for lithium and sodium ion batteries
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Samadi, M., Sarikhani, N., Zirak, M., Zhang, H., Zhang, H.-L., & Moshfegh, A. Z. (2018) · Nanoscale Horizons · doi:10.1039/c7nh00137a · Cited by 408
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Metadata
- Authors
- Niu, F., Yang, J., Wang, N., Zhang, D., Fan, W., Yang, J., & Qian, Y.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2017-04-21
- Volume
- 27
- Issue
- 23
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2605938571
- Cited by
- 543
- References
- 59
- FWCI
- 27.63
- Type
- journal article
- Language
- en
- Open access
- closed
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- Niu, F., Yang, J., Wang, N., Zhang, D., Fan, W., Yang, J., & Qian, Y. (2017). MoSe2‐Covered N,P‐Doped Carbon Nanosheets as a Long‐Life and High‐Rate Anode Material for Sodium‐Ion Batteries. Advanced Functional Materials. https://doi.org/10.1002/adfm.201700522
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