The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Atomic‐Scale CoOx Species in Metal–Organic Frameworks for Oxygen Evolution Reaction
Abstract
The activity of electrocatalysts strongly depends on the number of active sites, which can be increased by downsizing electrocatalysts. Single‐atom catalysts have attracted special attention due to atomic‐scale active sites. However, it is a huge challenge to obtain atomic‐scale CoOx catalysts. The Co‐based metal–organic frameworks (MOFs) own atomically dispersed Co ions, which motivates to design a possible pathway to partially on‐site transform these Co ions to active atomic‐scale CoOx species, while reserving the highly porous features of MOFs. In this work, for the first time, the targeted on‐site formation of atomic‐scale CoOx species is realized in ZIF‐67 by O 2 plasma. The abundant pores in ZIF‐67 provide channels for O 2 plasma to activate the Co ions in MOFs to on‐site produce atomic‐scale CoOx species, which act as the active sites to catalyze the oxygen evolution reaction with an even better activity than RuO 2.
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Cites
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Cited by
Su, J., Ge, R., Jiang, K., Dong, Y., Hao, F., Tian, Z., Chen, G., & Chen, L. (2018) · Advanced Materials · doi:10.1002/adma.201801351 · Cited by 544
Yu, P., Wang, F., Shifa, T. A., Zhan, X., Lou, X., Xia, F., & He, J. (2019) · Nano Energy · doi:10.1016/j.nanoen.2019.01.017 · Cited by 434
Recent Advances in MOF‐Derived Single Atom Catalysts for Electrochemical Applications
Song, Z., Zhang, L., Doyle‐Davis, K., Fu, X., Luo, J., & Sun, X. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202001561 · Cited by 412
Electrocatalysis of Single-Atom Sites: Impacts of Atomic Coordination
Lu, B., Liu, Q., & Chen, S. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01950 · Cited by 394
Cheng, N., Ren, L., Xu, X., Du, Y., & Dou, S. X. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201801257 · Cited by 359
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Metadata
- Authors
- Dou, S., Dong, C., Hu, Z., Huang, Y., Chen, J., Tao, L., Yan, D., Chen, D., Shen, S., Chou, S., & Wang, S.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2017-08-03
- Volume
- 27
- Issue
- 36
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2743154915
- Cited by
- 384
- References
- 3
- FWCI
- 16.22
- Type
- journal article
- Language
- en
- Open access
- closed
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