The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Multiple H‐Bonding Chain Extender‐Based Ultrastiff Thermoplastic Polyurethanes with Autonomous Self‐Healability, Solvent‐Free Adhesiveness, and AIE Fluorescence
Abstract
Developing an autonomous room temperature self‐healing supramolecular polyurethane (PU) with toughness and stiffness remains a great challenge. Herein, a novel concept that utilizes a T‐shaped chain extender with double amide hydrogen bonds in a side chain to extend PU prepolymers to construct highly stiff and tough supramolecular PU with integrated functions is reported. Mobile side‐chain H‐bonds afford a large flexibility to modulate the stiffness of the PUs ranging from highly stiff and tough elastomer (105.87 MPa Young's modulus, 27 kJ m−2 tearing energy), to solvent‐free hot‐melt adhesive, and coating. The dynamic side‐chain multiple H‐bonds afford an autonomous self‐healability at room temperature (25 °C). Due to the rapid reconstruction of hydrogen bonds, this PU adhesive demonstrates a high adhesion strength, fast curing, reusability, long‐term adhesion, and excellent low‐temperature resistance. Intriguingly, the PU emits intrinsic blue fluorescence presumably owing to the aggregation‐induced emission of tertiary amine domains induced by side‐chain H‐bonds. The PU is explored as a counterfeit ink coated on the predesigned pattern, which is visible‐light invisible and UV‐light visible. This work represents a universal and facile approach to fabricate supertough supramolecular PU with tailorable functions by chain extension of PU prepolymers with multiple H‐bonding chain extenders.
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Cites
Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole
Luo, J., Xie, Z., Lam, J. W. Y., Cheng, L., Tang, B. Z., Chen, H., Qiu, C., Kwok, H. S., Zhan, X., Liu, Y., et al. (2001) · Chemical Communications · doi:10.1039/b105159h · Cited by 8,358
Supramolecular materials based on AIE luminogens (AIEgens): construction and applications
Li, J., Wang, J., Li, H., Song, N., Wang, D., & Tang, B. Z. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00495e · Cited by 741
Chen, S., Mo, F., Yang, Y., Stadler, F. J., Chen, S., Yang, H., & Ge, Z. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06304j · Cited by 126
Cited by
Xu, J., Wang, X., Zhang, X., Zhang, Y., Yang, Z., Li, S., Tao, L., Wang, Q., & Wang, T. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2022.138673 · Cited by 284
Zhu, X., Zhang, W., Lu, G., Zhao, H., & Wang, L. (2022) · ACS Nano · doi:10.1021/acsnano.2c06264 · Cited by 279
Huang, L., Yang, Y., Shao, J., Xiong, G., Wang, H., Nishiura, M., & Hou, Z. (2024) · Journal of the American Chemical Society · doi:10.1021/jacs.3c12342 · Cited by 54
Metadata
- Authors
- Yao, Y., Xu, Z., Liu, B., Xiao, M., Yang, J., & Liu, W.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2020-10-09
- Volume
- 31
- Issue
- 4
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W3092071448
- Cited by
- 335
- References
- 3
- FWCI
- 12.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yao, Y., Xu, Z., Liu, B., Xiao, M., Yang, J., & Liu, W. (2021). Multiple H‐Bonding Chain Extender‐Based Ultrastiff Thermoplastic Polyurethanes with Autonomous Self‐Healability, Solvent‐Free Adhesiveness, and AIE Fluorescence. Advanced Functional Materials. https://doi.org/10.1002/adfm.202006944
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