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Highly Efficient Room‐Temperature Phosphorescence Based on Single‐Benzene Structure Molecules and Photoactivated Luminescence with Afterglow
Abstract
Recently, a remarkable advance has been made for metal‐free room‐temperature phosphorescence (RTP) crystals with high phosphorescence quantum yield. However, amorphous, especially heavy‐atom‐free, RTP materials still suffer from low quantum yield due to the transition‐forbidden character of phosphorescence and the relatively poor suppression of nonradiative transition in amorphous materials. In this study, a series of single‐benzene structure‐based high intersystem crossing yield phosphor is obtained. After embedding into polyvinyl alcohol matrix, all these phosphor exhibits efficient phosphorescence emission (Ф P, up to 44.0%). Besides, photo‐switchable phosphorescence emission can be obtained by doping these molecules into a polymethyl methacrylate (PMMA) matrix. The phosphorescence can be gradually switched on by consuming the residual oxygen in the PMMA matrix under continuous UV light irradiation. Furthermore, the phosphorescence will be spontaneously switched off under ambient conditions. Taking advantage of the photoactivation character, this material has potential in information storage and anti‐counterfeiting.
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Ma, H., Peng, Q., An, Z., Huang, W., & Shuai, Z. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.8b11224 · Cited by 613
Cited by
Large-Area, Flexible, Transparent, and Long-Lived Polymer-Based Phosphorescence Films
Zhang, Y., Su, Y., Wu, H., Wang, Z., Wang, C., Zheng, Y., Zheng, X., Gao, L., Zhou, Q., Yang, Y., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.1c05213 · Cited by 544
Li, D., Yang, J., Fang, M., Tang, B. Z., & Li, Z. (2022) · Science Advances · doi:10.1126/sciadv.abl8392 · Cited by 348
Metadata
- Authors
- Ma, L., Sun, S., Ding, B., Ma, X., & Tian, H.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2021-02-19
- Volume
- 31
- Issue
- 17
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W3131059478
- Cited by
- 254
- References
- 1
- FWCI
- 13.74
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ma, L., Sun, S., Ding, B., Ma, X., & Tian, H. (2021). Highly Efficient Room‐Temperature Phosphorescence Based on Single‐Benzene Structure Molecules and Photoactivated Luminescence with Afterglow. Advanced Functional Materials. https://doi.org/10.1002/adfm.202010659
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