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Highly Efficient Room‐Temperature Phosphorescence Based on Single‐Benzene Structure Molecules and Photoactivated Luminescence with Afterglow

Ma, Liangwei, Sun, Siyu, Ding, Bingbing, Ma, Xiang, Tian, He·2021·Advanced Functional Materials

Abstract

Recently, a remarkable advance has been made for metal‐free room‐temperature phosphorescence (RTP) crystals with high phosphorescence quantum yield. However, amorphous, especially heavy‐atom‐free, RTP materials still suffer from low quantum yield due to the transition‐forbidden character of phosphorescence and the relatively poor suppression of nonradiative transition in amorphous materials. In this study, a series of single‐benzene structure‐based high intersystem crossing yield phosphor is obtained. After embedding into polyvinyl alcohol matrix, all these phosphor exhibits efficient phosphorescence emission (Ф P, up to 44.0%). Besides, photo‐switchable phosphorescence emission can be obtained by doping these molecules into a polymethyl methacrylate (PMMA) matrix. The phosphorescence can be gradually switched on by consuming the residual oxygen in the PMMA matrix under continuous UV light irradiation. Furthermore, the phosphorescence will be spontaneously switched off under ambient conditions. Taking advantage of the photoactivation character, this material has potential in information storage and anti‐counterfeiting.

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Metadata

Authors
Ma, L., Sun, S., Ding, B., Ma, X., & Tian, H.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2021-02-19
Volume
31
Issue
17
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W3131059478
Cited by
254
References
1
FWCI
13.74
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Highly Efficient Room‐Temperature Phosphorescence Based on Single‐Benzene Structure Molecules and Photoactivated Luminescence with Afterglow. https://app.cochat.ai/papers/10.1002/adfm.202010659
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Ma, L., Sun, S., Ding, B., Ma, X., & Tian, H. (2021). Highly Efficient Room‐Temperature Phosphorescence Based on Single‐Benzene Structure Molecules and Photoactivated Luminescence with Afterglow. Advanced Functional Materials. https://doi.org/10.1002/adfm.202010659

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