The development of a high‐performance electrocatalyst for oxygen evolution reaction (OER) is imperative but challenging. Here, a partial sulfidation route to construct Ni2Fe‐LDH/FeNi2S4 heterostructure on nickel foam (Ni2Fe‐LDH/FeNi2S4/NF) by adjusting the hydrothermal duration is reported. The h…