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Substrate‐induced lateral micro‐phase separation of a diblock copolymer
Abstract
“Ultra‐monomolecular” films of block copolymers, i.e., films whose surface concentration is so low that the substrate cannot be covered homogeneously without affecting the structure of the macromolecules very strongly, have been studied using tapping‐ and friction‐mode SFM. Two‐dimensional phase separation yielding an ordered pattern of polystyrene and poly‐2‐vinylpyridine surface domains is observed. SFM is shown to distinguish topological features and also to discriminate between chemically different components. The surface features generated and the formation mechanisms involved are discussed.
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Citations
Cited by
Ghosh, S. K., & Pal, T. (2007) · Chemical Reviews · doi:10.1021/cr0680282 · Cited by 2,782
Nanocomposite Materials for Optical Applications
Beecroft, L. L., & Ober, C. K. (1997) · Chemistry of Materials · doi:10.1021/cm960441a · Cited by 1,019
Block copolymer based nanostructures: Materials, processes, and applications to electronics
Kim, H.-C., Park, S.-M., & Hinsberg, W. D. (2010) · Chemical Reviews · doi:10.1021/cr900159v · Cited by 1,017
Nanostructure fabrication using block copolymers
Hamley, I. W. (2003) · Nanotechnology · doi:10.1088/0957-4484/14/10/201 · Cited by 773
Using Cylindrical Domains of Block Copolymers To Self-Assemble and Align Metallic Nanowires
Chai, J., & Buriak, J. M. (2008) · ACS Nano · doi:10.1021/nn700341s · Cited by 317
Metadata
- Authors
- Spatz, J. P., Sheiko, S., & Möller, M.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 1996-06
- Volume
- 8
- Issue
- 6
- Pages
- 513-517
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W1995854309
- Cited by
- 406
- References
- 0
- FWCI
- 27.36
- Type
- journal article
- Language
- en
- Open access
- closed
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- Spatz, J. P., Sheiko, S., & Möller, M. (1996). Substrate‐induced lateral micro‐phase separation of a diblock copolymer. Advanced Materials. https://doi.org/10.1002/adma.19960080614
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