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Photoresponsive Anisotropic Soft Solids: Liquid‐Crystalline Physical Gels Based on a Chiral Photochromic Gelator
Abstract
Photoinduced reversible structural changes of anisotropic physical gels are applied to re‐writable patterning (see Figure, a photo of a re‐writable pattern). The change between a nematic gel and a cholesteric gel via a cholesteric liquid‐crystalline sol state is induced by trans–cis photoisomerization of the azobenzene moieties in a chiral hydrogen‐bonded gelator blended with a nematic liquid crystal.
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About Supramolecular Assemblies of π-Conjugated Systems
Hoeben, F. J. M., Jonkheijm, P., Meijer, E. W., & Schenning, A. P. H. J. (2005) · Chemical Reviews · doi:10.1021/cr030070z · Cited by 3,096
Supramolecular gels: Functions and uses
Sangeetha, N. M., & Maitra, U. (2005) · Chemical Society Reviews · doi:10.1039/b417081b · Cited by 2,045
Functional π-Gelators and Their Applications
Babu, S. S., Praveen, V. K., & Ajayaghosh, A. (2014) · Chemical Reviews · doi:10.1021/cr400195e · Cited by 1,725
Functional Liquid‐Crystalline Assemblies: Self‐Organized Soft Materials
Kato, T., Mizoshita, N., & Kishimoto, K. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200501384 · Cited by 1,545
Self-citationBisoyi, H. K., & Li, Q. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00415 · Cited by 929
Metadata
- Authors
- Moriyama, M., Mizoshita, N., Yokota, T., Kishimoto, K., & Kato, T.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2003-08-15
- Volume
- 15
- Issue
- 16
- Pages
- 1335-1338
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2102705830
- Cited by
- 177
- References
- 0
- FWCI
- 7.14
- Type
- journal article
- Language
- en
- Open access
- closed
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- Moriyama, M., Mizoshita, N., Yokota, T., Kishimoto, K., & Kato, T. (2003). Photoresponsive Anisotropic Soft Solids: Liquid‐Crystalline Physical Gels Based on a Chiral Photochromic Gelator. Advanced Materials. https://doi.org/10.1002/adma.200305056
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