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Hydrogen Physisorption in Metal–Organic Porous Crystals
Abstract
Hydrogen adsorption in microporous solid materials may enable H2 to be stored at lower pressures than in compressed-gas tanks, and at higher temperatures than for liquid H2. A new class of metal–organic frameworks (MOFs) with a high specific surface area appears promising for H2 storage. Here, the H2-uptake capacity of MOF-5 over a wide pressure range, at room temperature and at 77 K is investigated (see Figure). Adsorption of H2 exclusively in the micropores of these metal–organic frameworks is demonstrated.
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Recent advances in crystal engineering
Aakeröy, C. B., Champness, N. R., & Janiak, C. (2010) · CrystEngComm · doi:10.1039/b919819a · Cited by 746
Han, S. S., Mendoza-Cortés, J. L., & Goddard III, W. A. (2009) · Chemical Society Reviews · doi:10.1039/b802430h · Cited by 594
Nanoporous Polymers for Hydrogen Storage
Germain, J., Fréchet, J. M. J., & Svec, F. (2009) · Small · doi:10.1002/smll.200801762 · Cited by 432
Energy-based descriptors to rapidly predict hydrogen storage in metal–organic frameworks
Bucior, B. J., Bobbitt, N. S., Islamoglu, T., Goswami, S., Gopalan, A., Yildirim, T., Farha, O. K., Bagheri, N., & Snurr, R. Q. (2019) · Molecular Systems Design & Engineering · doi:10.1039/c8me00050f · Cited by 308
Metal–organic frameworks (MOFs): potential and challenges for capture and abatement of ammonia
Vikrant, K., Kumar, V., Kim, K.-H., & Kukkar, D. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta07847a · Cited by 299
Metadata
- Authors
- Panella, B., & Hirscher, M.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2005-03-03
- Volume
- 17
- Issue
- 5
- Pages
- 538-541
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2055345420
- Cited by
- 329
- References
- 0
- FWCI
- 17.61
- Type
- journal article
- Language
- en
- Open access
- closed
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