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Fmoc‐Diphenylalanine Self Assembles to a Hydrogel via a Novel Architecture Based on π–π Interlocked β‐Sheets

Open access
Smith, A. M., Williams, R. J., Tang, C., Coppo, P., Collins, R. F., Turner, M. L., Saiani, A., Ulijn, R. V.·2008·Advanced Materials

Abstract

The self assembly of peptide hydrogelators that carry aromatic substituents can be modeled by a novel nanocylindrical architecture. The proposed model suggests that the nanocylinders are formed by anti-parallel β-sheets interlocked by the π-stacking interactions of fluorenyl groups and phenyl rings. This explanation is consistent with the structures observed in TEM and the data obtained by a variety of spectroscopic techniques.

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Metadata

Authors
Smith, A. M., Williams, R. J., Tang, C., Coppo, P., Collins, R. F., Turner, M. L., Saiani, A., & Ulijn, R. V.
Venue
Advanced Materials
Publisher
Wiley
Published
2007-12-11
Volume
20
Issue
1
Pages
37-41
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2047726172
Cited by
995
References
0
FWCI
13.17
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Fmoc‐Diphenylalanine Self Assembles to a Hydrogel via a Novel Architecture Based on π–π Interlocked β‐Sheets. https://app.cochat.ai/papers/10.1002/adma.200701221
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Smith, A. M., Williams, R. J., Tang, C., Coppo, P., Collins, R. F., Turner, M. L., Saiani, A., & Ulijn, R. V. (2008). Fmoc‐Diphenylalanine Self Assembles to a Hydrogel via a Novel Architecture Based on π–π Interlocked β‐Sheets. Advanced Materials. https://doi.org/10.1002/adma.200701221

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.