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Towards Solutions of Single‐Walled Carbon Nanotubes in Common Solvents
Abstract
Spontaneous exfoliation of single-walled carbon nanotubes on dilution of dispersions in a common solvent, N-methyl-pyrrolidone, is demonstrated. The free-energy of mixing is negative, confirming athermal solubility. Scanning tunneling microscopy measurements show physisorption of the solvent to the nanotube (see figure). Experiments, supported by a simple model, show that successful solvents for nanotubes are those with surface tensions close to that of graphite.
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Citations
Cites
Introduction to Physical Polymer Science
Sperling, L. H. (2005) · doi:10.1002/0471757128 · Cited by 2,917
Cited by
Recent Advances in Research on Carbon Nanotube–Polymer Composites
Byrne, M. T., & Gun'ko, Y. K. (2010) · Advanced Materials · doi:10.1002/adma.200901545 · Cited by 873
Wang, H., Zeng, Z., Xu, P., Li, L., Zeng, G., Xiao, R., Tang, Z., Huang, D., Tang, L., Lai, C., et al. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00376a · Cited by 804
Samadi, M., Sarikhani, N., Zirak, M., Zhang, H., Zhang, H.-L., & Moshfegh, A. Z. (2018) · Nanoscale Horizons · doi:10.1039/c7nh00137a · Cited by 408
Metadata
- Authors
- Bergin, S. D., Nicolosi, V., Streich, P. V., Giordani, S., Sun, Z., Windle, A. H., Ryan, P., Niraj, N. P. P., Wang, Z. T., Carpenter, L., Blau, W. J., Boland, J. J., Hamilton, J. P., & Coleman, J. N.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2008-05-19
- Volume
- 20
- Issue
- 10
- Pages
- 1876-1881
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2124393739
- Cited by
- 354
- References
- 1
- FWCI
- 17.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- Bergin, S. D., Nicolosi, V., Streich, P. V., Giordani, S., Sun, Z., Windle, A. H., Ryan, P., Niraj, N. P. P., Wang, Z. T., Carpenter, L., Blau, W. J., Boland, J. J., Hamilton, J. P., & Coleman, J. N. (2008). Towards Solutions of Single‐Walled Carbon Nanotubes in Common Solvents. Advanced Materials. https://doi.org/10.1002/adma.200702451
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.