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Zeolitic Materials with Hierarchical Porous Structures
Abstract
During the past several years, different kinds of hierarchical structured zeolitic materials have been synthesized due to their highly attractive properties, such as superior mass/heat transfer characteristics, lower restriction of the diffusion of reactants in the mesopores, and low pressure drop. Our contribution provides general information regarding types and preparation methods of hierarchical zeolitic materials and their relative advantages and disadvantages. Thereafter, recent advances in the preparation and characterization of hierarchical zeolitic structures within the crystallites by post‐synthetic treatment methods, such as dealumination or desilication; and structured devices by in situ and ex situ zeolite coatings on open‐cellular ceramic foams as (non‐reactive as well as reactive) supports are highlighted. Specific advantages of using hierarchical zeolitic catalysts/structures in selected catalytic reactions, such as benzene to phenol (BTOP) and methanol to olefins (MTO) are presented.
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Cites
Ordered porous materials for emerging applications
Davis, M. E. (2002) · Nature · doi:10.1038/nature00785 · Cited by 5,308
The ITQ-37 mesoporous chiral zeolite
Sun, J., Bonneau, C., Cantín, Á., Corma, A., Díaz-Cabañas, M. J., Moliner, M., Zhang, D., Li, M., & Zou, X. (2009) · Nature · doi:10.1038/nature07957 · Cited by 581
Cited by
Hierarchical porous materials: catalytic applications
Parlett, C. M. A., Wilson, K., & Lee, A. F. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35378d · Cited by 955
Hierarchically Structured Zeolites: From Design to Application
Chen, L.-H., Sun, M.-H., Wang, Z., Yang, W., Xie, Z., & Su, B.-L. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00016 · Cited by 724
Mesoporous materials for clean energy technologies
Linares, N., Silvestre-Albero, A. M., Serrano, E., Silvestre-Albero, J., & García-Martínez, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60435g · Cited by 526
Recent Progress in Methanol‐to‐Olefins (MTO) Catalysts
Yang, M., Fan, D., Wei, Y., Tian, P., & Liu, Z. (2019) · Advanced Materials · doi:10.1002/adma.201902181 · Cited by 417
Hierarchical Y and USY Zeolites Designed by Post‐Synthetic Strategies
Verboekend, D., Vilé, G., & Pérez‐Ramírez, J. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201102411 · Cited by 364
Metadata
- Authors
- Lopez‐Orozco, S., Inayat, A., Schwab, A., Selvam, T., & Schwieger, W.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2011-04-15
- Volume
- 23
- Issue
- 22-23
- Pages
- 2602-2615
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2108164650
- Cited by
- 389
- References
- 2
- FWCI
- 16.98
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lopez‐Orozco, S., Inayat, A., Schwab, A., Selvam, T., & Schwieger, W. (2011). Zeolitic Materials with Hierarchical Porous Structures. Advanced Materials. https://doi.org/10.1002/adma.201100462
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