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Highly Emissive Green Perovskite Nanocrystals in a Solid State Crystalline Matrix
Open accessAbstract
Perovskite nanocrystals (NCs) have attracted attention due to their high photoluminescence quantum yield (PLQY) in solution; however, maintaining high emission efficiency in the solid state remains a challenge. This study presents a solution‐phase synthesis of efficient green‐emitting perovskite NCs (CsPbBr 3) embedded in robust and air‐stable rhombic prism hexabromide (Cs 4 PbBr 6) microcrystals, reaching a PLQY of 90%. Theoretical modeling and experimental characterization suggest that lattice matching between the NCs and the matrix contribute to improved passivation, while spatial confinement enhances the radiative rate of the NCs. In addition, dispersing the NCs in a matrix prevents agglomeration, which explains their high PLQY.
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Akkerman, Q. A., D’Innocenzo, V., Accornero, S., Scarpellini, A., Petrozza, A., Prato, M., & Manna, L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b05602 · Cited by 2,197
Structured Organic–Inorganic Perovskite toward a Distributed Feedback Laser
Saliba, M., Wood, S. M., Patel, J. B., Nayak, P. K., Huang, J., Alexander‐Webber, J. A., Wenger, B., Stranks, S. D., Hörantner, M. T., Wang, J. T., et al. (2016) · Advanced Materials · doi:10.1002/adma.201502608 · Cited by 297
Cited by
Genesis, challenges and opportunities for colloidal lead halide perovskite nanocrystals
Akkerman, Q. A., Rainò, G., Kovalenko, M. V., & Manna, L. (2018) · Nature Materials · doi:10.1038/s41563-018-0018-4 · Cited by 2,287
Wei, Y., Cheng, Z., & Lin, J. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00740c · Cited by 1,206
Krieg, F., Ochsenbein, S. T., Yakunin, S., ten Brinck, S., Aellen, P., Süess, A., Clerc, B., Guggisberg, D., Nazarenko, O., Shynkarenko, Y., et al. (2018) · ACS Energy Letters · doi:10.1021/acsenergylett.8b00035 · Cited by 893
Bodnarchuk, M. I., Boehme, S. C., ten Brinck, S., Bernasconi, C., Shynkarenko, Y., Krieg, F., Widmer, R., Aeschlimann, B., Günther, D., Kovalenko, M. V., et al. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01669 · Cited by 466
The Many “Facets” of Halide Ions in the Chemistry of Colloidal Inorganic Nanocrystals
Ghosh, S., & Manna, L. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00158 · Cited by 325
Metadata
- Authors
- Quan, L. N., Quintero‐Bermudez, R., Voznyy, O., Walters, G., Jain, A., Fan, J. Z., Zheng, X., Yang, Z., & Sargent, E. H.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2017-03-29
- Volume
- 29
- Issue
- 21
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2598461673
- Cited by
- 374
- References
- 2
- FWCI
- 19.91
- Type
- journal article
- Language
- en
- Open access
- green
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- Quan, L. N., Quintero‐Bermudez, R., Voznyy, O., Walters, G., Jain, A., Fan, J. Z., Zheng, X., Yang, Z., & Sargent, E. H. (2017). Highly Emissive Green Perovskite Nanocrystals in a Solid State Crystalline Matrix. Advanced Materials. https://doi.org/10.1002/adma.201605945
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