The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Cations in Octahedral Sites: A Descriptor for Oxygen Electrocatalysis on Transition‐Metal Spinels
Open accessAbstract
Exploring efficient and low‐cost electrocatalysts for the oxygen‐reduction reaction (ORR) and oxygen‐evolution reaction (OER) is critical for developing renewable energy technologies such as fuel cells, metal–air batteries, and water electrolyzers. A rational design of a catalyst can be guided by identifying descriptors that determine its activity. Here, a descriptor study on the ORR/OER of spinel oxides is presented. With a series of MnCo 2 O 4, the Mn in octahedral sites is identified as an active site. This finding is then applied to successfully explain the ORR/OER activities of other transition‐metal spinels, including MnxCo 3−xO 4 (x = 2, 2.5, 3), LixMn 2 O 4 (x = 0.7, 1), XCo 2 O 4 (X = Co, Ni, Zn), and XFe 2 O 4 (X = Mn, Co, Ni). A general principle is concluded that the e g occupancy of the active cation in the octahedral site is the activity descriptor for the ORR/OER of spinels, consolidating the role of electron orbital filling in metal oxide catalysis.
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Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
Gasteiger, H. A., Kocha, S. S., Sompalli, B., & Wagner, F. T. (2005) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2004.06.021 · Cited by 4,876
Improved Oxygen Reduction Activity on Pt 3 Ni(111) via Increased Surface Site Availability
Stamenkovic, V. R., Fowler, B., Mun, B. S., Wang, G., Ross, P. N., Lucas, C. A., & Marković, N. M. (2007) · Science · doi:10.1126/science.1135941 · Cited by 4,421
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Self-citationHydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes
Sheng, W., Gasteiger, H. A., & Shao-Horn, Y. (2010) · Journal of The Electrochemical Society · doi:10.1149/1.3483106 · Cited by 1,829
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Jung, S., McCrory, C. C. L., Ferrer, I. M., Peters, J. C., & Jaramillo, T. F. (2016) · Journal of Materials Chemistry A · doi:10.1039/c5ta07586f · Cited by 600
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Self-citationChatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
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Zhu, Z., Jiang, T., Ali, M., Meng, Y., Jin, Y., Cui, Y., & Chen, W. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00289 · Cited by 1,769
Xiao, Z., Huang, Y.-C., Dong, C.-L., Xie, C., Liu, Z., Du, S., Chen, W., Yan, D., Tao, L., Shu, Z., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c00257 · Cited by 1,445
Wu, T., Sun, S., Song, J., Xi, S., Du, Y., Chen, B., Sasangka, W. A., Liao, H., Gan, C. L., Scherer, G. G., et al. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0325-4 · Cited by 1,050
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Metadata
- Authors
- Wei, C., Feng, Z., Scherer, G. G., Barber, J., Shao‐Horn, Y., & Xu, Z. J.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2017-04-10
- Volume
- 29
- Issue
- 23
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2606017501
- Cited by
- 810
- References
- 6
- FWCI
- 17.43
- Type
- journal article
- Language
- en
- Open access
- green
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- Wei, C., Feng, Z., Scherer, G. G., Barber, J., Shao‐Horn, Y., & Xu, Z. J. (2017). Cations in Octahedral Sites: A Descriptor for Oxygen Electrocatalysis on Transition‐Metal Spinels. Advanced Materials. https://doi.org/10.1002/adma.201606800
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