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Two Well‐Miscible Acceptors Work as One for Efficient Fullerene‐Free Organic Solar Cells

Yu, Runnan, Zhang, Shaoqing, Yao, Huifeng, Guo, Bing, Li, Sunsun, Zhang, Hao, Zhang, Maojie, Hou, Jianhui·2017·Advanced Materials

Abstract

High‐performance ternary organic solar cells are fabricated by using a wide‐bandgap polymer donor (bithienyl‐benzodithiophene‐alt‐fluorobenzotriazole copolymer, J52) and two well‐miscible nonfullerene acceptors, methyl‐modified nonfullerene acceptor (IT‐M) and 2,2′‐((2 Z,2′Z)‐((5,5′‐(4,4,9,9‐tetrakis(4‐hexylphenyl)‐4,9‐dihydros‐indaceno[1,2‐b:5,6‐b′]dithiophene‐2,7‐diyl)bis(4‐((2‐ethylhexyl)oxy)thiophene‐5,2‐diyl))bis(methanylylidene))bis(3‐oxo‐2,3‐dihydro‐1 H‐indene‐2,1‐diylidene))dimalononitrile (IEICO). The two acceptors with complementary absorption spectra and similar lowest unoccupied molecular orbital levels show excellent compatibility in the blend due to their very similar chemical structures. Consequently, the obtained ternary organic solar cells (OSC) exhibits a high efficiency of 11.1%, with an enhanced short‐circuit current density of 19.7 mA cm−2 and a fill factor of 0.668. In this ternary system, broadened absorption, similar output voltages, and compatible morphology are achieved simultaneously, demonstrating a promising strategy to further improve the performance of ternary OSCs.

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Metadata

Authors
Yu, R., Zhang, S., Yao, H., Guo, B., Li, S., Zhang, H., Zhang, M., & Hou, J.
Venue
Advanced Materials
Publisher
Wiley
Published
2017-05-03
Volume
29
Issue
26
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2610495454
Cited by
170
References
2
FWCI
13.87
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Two Well‐Miscible Acceptors Work as One for Efficient Fullerene‐Free Organic Solar Cells. https://app.cochat.ai/papers/10.1002/adma.201700437
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Yu, R., Zhang, S., Yao, H., Guo, B., Li, S., Zhang, H., Zhang, M., & Hou, J. (2017). Two Well‐Miscible Acceptors Work as One for Efficient Fullerene‐Free Organic Solar Cells. Advanced Materials. https://doi.org/10.1002/adma.201700437

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