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Cited by 382

The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.

Self‐Assembled Au/CdSe Nanocrystal Clusters for Plasmon‐Mediated Photocatalytic Hydrogen Evolution

Shi, Run, Cao, Yinhu, Bao, Yanjun, Zhao, Yufei, Waterhouse, Geoffrey I. N., Fang, Zheyu, Wu, Li‐Zhu, Tung, Chen‐Ho, Yin, Yadong, Zhang, Tierui·2017·Advanced Materials

Abstract

Plasmon‐mediated photocatalytic systems generally suffer from poor efficiency due to weak absorption overlap and thus limited energy transfer between the plasmonic metal and the semiconductor. Herein, a near‐ideal plasmon‐mediated photocatalyst system is developed. Au/CdSe nanocrystal clusters (NCs) are successfully fabricated through a facile emulsion‐based self‐assembly approach, containing Au nanoparticles (NPs) of size 2.8, 4.6, 7.2, or 9.0 nm and CdSe quantum dots (QDs) of size ≈3.3 nm. Under visible‐light irradiation, the Au/CdSe NCs with 7.2 nm Au NPs afford very stable operation and a remarkable H 2‐evolution rate of (10× higher than bare CdSe NCs). Plasmon resonance energy transfer from the Au NPs to the CdSe QDs, which enhances charge‐carrier generation in the semiconductor and suppresses bulk recombination, is responsible for the outstanding photocatalytic performance. The approach used here to fabricate the Au/CdSe NCs is suitable for the construction of other plasmon‐mediated photocatalysts.

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Metadata

Authors
Shi, R., Cao, Y., Bao, Y., Zhao, Y., Waterhouse, G. I. N., Fang, Z., Wu, L., Tung, C., Yin, Y., & Zhang, T.
Venue
Advanced Materials
Publisher
Wiley
Published
2017-05-12
Volume
29
Issue
27
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2612302069
Cited by
382
References
32
FWCI
14.52
Type
journal article
Language
en
Open access
closed

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Shi, R., Cao, Y., Bao, Y., Zhao, Y., Waterhouse, G. I. N., Fang, Z., Wu, L., Tung, C., Yin, Y., & Zhang, T. (2017). Self‐Assembled Au/CdSe Nanocrystal Clusters for Plasmon‐Mediated Photocatalytic Hydrogen Evolution. Advanced Materials. https://doi.org/10.1002/adma.201700803

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