The DOI matches its Crossref record; 32 of the 32 references it cites were found in a registry or an index.
Self‐Assembled Au/CdSe Nanocrystal Clusters for Plasmon‐Mediated Photocatalytic Hydrogen Evolution
Abstract
Plasmon‐mediated photocatalytic systems generally suffer from poor efficiency due to weak absorption overlap and thus limited energy transfer between the plasmonic metal and the semiconductor. Herein, a near‐ideal plasmon‐mediated photocatalyst system is developed. Au/CdSe nanocrystal clusters (NCs) are successfully fabricated through a facile emulsion‐based self‐assembly approach, containing Au nanoparticles (NPs) of size 2.8, 4.6, 7.2, or 9.0 nm and CdSe quantum dots (QDs) of size ≈3.3 nm. Under visible‐light irradiation, the Au/CdSe NCs with 7.2 nm Au NPs afford very stable operation and a remarkable H 2‐evolution rate of (10× higher than bare CdSe NCs). Plasmon resonance energy transfer from the Au NPs to the CdSe QDs, which enhances charge‐carrier generation in the semiconductor and suppresses bulk recombination, is responsible for the outstanding photocatalytic performance. The approach used here to fabricate the Au/CdSe NCs is suitable for the construction of other plasmon‐mediated photocatalysts.
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Cites
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Cited by
Yang, M., Gao, M., Hong, M., & Ho, G. W. (2018) · Advanced Materials · doi:10.1002/adma.201802894 · Cited by 389
Emerging Hierarchical Aerogels: Self‐Assembly of Metal and Semiconductor Nanocrystals
Cai, B., Sayevich, V., Gaponik, N., & Eychmüller, A. (2018) · Advanced Materials · doi:10.1002/adma.201707518 · Cited by 136
Metadata
- Authors
- Shi, R., Cao, Y., Bao, Y., Zhao, Y., Waterhouse, G. I. N., Fang, Z., Wu, L., Tung, C., Yin, Y., & Zhang, T.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2017-05-12
- Volume
- 29
- Issue
- 27
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2612302069
- Cited by
- 382
- References
- 32
- FWCI
- 14.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shi, R., Cao, Y., Bao, Y., Zhao, Y., Waterhouse, G. I. N., Fang, Z., Wu, L., Tung, C., Yin, Y., & Zhang, T. (2017). Self‐Assembled Au/CdSe Nanocrystal Clusters for Plasmon‐Mediated Photocatalytic Hydrogen Evolution. Advanced Materials. https://doi.org/10.1002/adma.201700803
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