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Cerium and Ytterbium Codoped Halide Perovskite Quantum Dots: A Novel and Efficient Downconverter for Improving the Performance of Silicon Solar Cells
Abstract
Quantum cutting can realize the emission of multiple near‐infrared photons for each ultraviolet/visible photon absorbed, and has potential to significantly improve the photoelectric conversion efficiency (PCE) of solar cells. However, due to the lack of an ideal downconversion material, it has merely served as a principle in the laboratory until now. Here, the fabrication of a novel type of quantum cutting material, CsPbCl 1.5 Br 1.5:Yb 3+, Ce 3+ nanocrystals is presented. Benefiting from the larger absorption cross‐section, weaker electron–phonon coupling, and higher inner luminescent quantum yield (146%), the doped perovskite nanocrystals are successfully explored as a downconverter of commercial silicon solar cells (SSCs). Noticeably, the PCE of the SSCs is improved from 18.1% to 21.5%, with a relative enhancement of 18.8%. This work exhibits a cheap, convenient, and effective way to enhance the PCE of SSCs, which may be commercially popularized in the future.
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Citations
Cited by
Wei, Y., Cheng, Z., & Lin, J. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00740c · Cited by 1,206
Metal-Doped Lead Halide Perovskites: Synthesis, Properties, and Optoelectronic Applications
Zhou, Y., Chen, J., Bakr, O. M., & Sun, H.-T. (2018) · Chemistry of Materials · doi:10.1021/acs.chemmater.8b02989 · Cited by 650
Hao, M., Bai, Y., Zeiske, S., Ren, L., Liu, J., Yuan, Y., Zarrabi, N., Cheng, N., Ghasemi, M., Chen, P., et al. (2020) · Nature Energy · doi:10.1038/s41560-019-0535-7 · Cited by 587
Bi3+‐Er3+ and Bi3+‐Yb3+ Codoped Cs2AgInCl6 Double Perovskite Near‐Infrared Emitters
Arfin, H., Kaur, J., Sheikh, T., Chakraborty, S., & Nag, A. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202002721 · Cited by 359
Europium-Doped Lead-Free Cs 3 Bi 2 Br 9 Perovskite Quantum Dots and Ultrasensitive Cu 2+ Detection
Ding, N., Zhou, D., Pan, G., Xu, W., Chen, X., Li, D., Zhang, X., Zhu, J., Ji, Y., & Song, H. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b00038 · Cited by 171
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Metadata
- Authors
- Zhou, D., Liu, D., Pan, G., Chen, X., Li, D., Xu, W., Bai, X., & Song, H.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2017-09-29
- Volume
- 29
- Issue
- 42
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2759426645
- Cited by
- 516
- References
- 0
- FWCI
- 19.24
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Cerium and Ytterbium Codoped Halide Perovskite Quantum Dots: A Novel and Efficient Downconverter for Improving the Performance of Silicon Solar Cells. https://app.cochat.ai/papers/10.1002/adma.201704149
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- Zhou, D., Liu, D., Pan, G., Chen, X., Li, D., Xu, W., Bai, X., & Song, H. (2017). Cerium and Ytterbium Codoped Halide Perovskite Quantum Dots: A Novel and Efficient Downconverter for Improving the Performance of Silicon Solar Cells. Advanced Materials. https://doi.org/10.1002/adma.201704149
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