The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Solid Halide Electrolytes with High Lithium‐Ion Conductivity for Application in 4 V Class Bulk‐Type All‐Solid‐State Batteries
Abstract
New lithium halide solid‐electrolyte materials, Li 3 YCl 6 and Li 3 YBr 6, are found to exhibit high lithium‐ion conductivity, high deformability, and high chemical and electrochemical stability, which are required properties for all‐solid‐state battery (ASSB) applications, particularly for large‐scale deployment. The lithium‐ion conductivities of cold‐pressed powders surpass 1 mS cm−1 at room temperature without additional intergrain or grain boundary resistances. Bulk‐type ASSB cells employing these new halide solid electrolyte materials exhibit coulombic efficiencies as high as 94% with an active cathode material of LiCoO 2 without any extra coating. These superior electrochemical characteristics, as well as their material stability, indicate that lithium halide salts are another promising candidate for ASSB solid electrolytes in addition to sulfides or oxides.
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Shannon, R. D. (1976) · Acta Crystallographica Section A · doi:10.1107/s0567739476001551 · Cited by 66,145
Armand, M., & Tarascon, J.-M. (2008) · Nature · doi:10.1038/451652a · Cited by 19,612
A solid future for battery development
Janek, J., & Zeier, W. G. (2016) · Nature Energy · doi:10.1038/nenergy.2016.141 · Cited by 3,979
Interface Stability in Solid-State Batteries
Richards, W. D., Miara, L. J., Wang, Y., Kim, J. C., & Ceder, G. (2016) · Chemistry of Materials · doi:10.1021/acs.chemmater.5b04082 · Cited by 1,652
Cited by
High-safety separators for lithium-ion batteries and sodium-ion batteries: advances and perspective
Zhang, L., Li, X., Yang, M., & Chen, W. (2021) · Energy Storage Materials · doi:10.1016/j.ensm.2021.06.033 · Cited by 587
Kwak, H., Wang, S., Park, J., Liu, Y., Kim, K. T., Choi, Y., Mo, Y., & Jung, Y. S. (2022) · ACS Energy Letters · doi:10.1021/acsenergylett.2c00438 · Cited by 341
Fluorination in advanced battery design
Wang, Y., Wu, Z., Azad, F. M., Zhu, Y., Wang, L., Hawker, C. J., Whittaker, A. K., Forsyth, M., & Zhang, C. (2023) · Nature Reviews Materials · doi:10.1038/s41578-023-00623-4 · Cited by 333
Metadata
- Authors
- Asano, T., Sakai, A., Ouchi, S., Sakaida, M., Miyazaki, A., & Hasegawa, S.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2018-09-14
- Volume
- 30
- Issue
- 44
- Pages
- e1803075-e1803075
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2892260477
- Cited by
- 1,275
- References
- 4
- FWCI
- 19.00
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Asano, T., Sakai, A., Ouchi, S., Sakaida, M., Miyazaki, A., & Hasegawa, S. (2018). Solid Halide Electrolytes with High Lithium‐Ion Conductivity for Application in 4 V Class Bulk‐Type All‐Solid‐State Batteries. Advanced Materials. https://doi.org/10.1002/adma.201803075
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