The DOI matches its Crossref record; 31 of the 31 references it cites were found in a registry or an index.
Detrimental Effect of Unreacted PbI2 on the Long‐Term Stability of Perovskite Solar Cells
Abstract
Excess/unreacted lead iodide (PbI 2) has been commonly used in perovskite films for the state‐of‐the‐art solar cell applications. However, an understanding of intrinsic degradation mechanisms of perovskite solar cells (PSCs) containing unreacted PbI 2 has been still insufficient and, therefore, needs to be clarified for better operational durability. Here, it is shown that degradation of PSCs is hastened by unreacted PbI 2 crystals under continuous light illumination. Unreacted PbI 2 undergoes photodecomposition under illumination, resulting in the formation of lead and iodine in films. Thus, this photodecomposition of PbI 2 is one of the main reasons for accelerated device degradation. Therefore, this work reveals that carefully controlling the formation of unreacted PbI 2 crystals in perovskite films is very important to improve device operational stability for diverse opto‐electronic applications in the future.
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Cites
Ror2 signaling regulates Golgi structure and transport through IFT20 for tumor invasiveness
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Incorporation of rubidium cations into perovskite solar cells improves photovoltaic performance
Saliba, M., Matsui, T., Domanski, K., Seo, J.-Y., Ummadisingu, A., Zakeeruddin, S. M., Correa-Baena, J.-P., Tress, W. R., Abate, A., Hagfeldt, A., et al. (2016) · Science · doi:10.1126/science.aah5557 · Cited by 3,706
Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes
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Maximizing and stabilizing luminescence from halide perovskites with potassium passivation
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Self-citation
Cited by
Origins and influences of metallic lead in perovskite solar cells
Liang, J., Hu, X., Wang, C., Liang, C., Chen, C., Xiao, M., Li, J., Tao, C., Xing, G., Yu, R., et al. (2022) · Joule · doi:10.1016/j.joule.2022.03.005 · Cited by 576
Tailoring passivators for highly efficient and stable perovskite solar cells
Zhang, H., Pfeifer, L., Zakeeruddin, S. M., Chu, J., & Grätzel, M. (2023) · Nature Reviews Chemistry · doi:10.1038/s41570-023-00510-0 · Cited by 386
Deng, Y., Xu, S., Chen, S., Xiao, X., Zhao, J., & Huang, J. (2021) · Nature Energy · doi:10.1038/s41560-021-00831-8 · Cited by 331
Metadata
- Authors
- Tumen‐Ulzii, G., Qin, C., Klotz, D., Leyden, M. R., Wang, P., Auffray, M., Fujihara, T., Matsushima, T., Lee, J., Lee, S., Yang, Y., & Adachi, C.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2020-02-27
- Volume
- 32
- Issue
- 16
- Pages
- e1905035-e1905035
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3008980269
- Cited by
- 466
- References
- 31
- FWCI
- 20.25
- Type
- journal article
- Language
- en
- Open access
- closed
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- Tumen‐Ulzii, G., Qin, C., Klotz, D., Leyden, M. R., Wang, P., Auffray, M., Fujihara, T., Matsushima, T., Lee, J., Lee, S., Yang, Y., & Adachi, C. (2020). Detrimental Effect of Unreacted PbI2 on the Long‐Term Stability of Perovskite Solar Cells. Advanced Materials. https://doi.org/10.1002/adma.201905035
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