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Devising Synthetic Reaction Cycles for Dissipative Nonequilibrium Self‐Assembly

Open access
Singh, Nishant, Formon, Georges J. M., De Piccoli, Serena, Hermans, Thomas M.·2020·Advanced Materials

Abstract

Fuel‐driven reaction cycles are found in biological systems to control the assembly and disassembly of supramolecular materials such as the cytoskeleton. Fuel molecules can bind noncovalently to a self‐assembling building block or they can react with it, resulting in covalent modifications. Overall the fuel can either switch the self‐assembly process on or off. Here, a closer look is taken at artificial systems that mimic biological systems by making and breaking covalent bonds in a self‐assembling motif. The different chemistries used so far are highlighted in chronological order and the pros and cons of each system are discussed. Moreover, the desired traits of future reaction cycles, their fuels, and waste management are outlined, and two chemistries that have not been explored up to now in chemically fueled dissipative self‐assembly are suggested.

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Metadata

Authors
Singh, N., Formon, G. J. M., De Piccoli, S., & Hermans, T. M.
Venue
Advanced Materials
Publisher
Wiley
Published
2020-02-16
Volume
32
Issue
20
Pages
e1906834-e1906834
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W3006399194
Cited by
166
References
2
FWCI
6.51
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Devising Synthetic Reaction Cycles for Dissipative Nonequilibrium Self‐Assembly. https://app.cochat.ai/papers/10.1002/adma.201906834
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Singh, N., Formon, G. J. M., De Piccoli, S., & Hermans, T. M. (2020). Devising Synthetic Reaction Cycles for Dissipative Nonequilibrium Self‐Assembly. Advanced Materials. https://doi.org/10.1002/adma.201906834

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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