The DOI matches its Crossref record; 44 of the 44 references it cites were found in a registry or an index.
De Novo Design of Covalent Organic Framework Membranes toward Ultrafast Anion Transport
Abstract
The emergence of all‐organic frameworks is of fundamental significance, and designing such structures for anion conduction holds great promise in energy conversion and storage applications. Herein, inspired by the efficient anion transport within organisms, a de novo design of covalent organic frameworks (COFs) toward ultrafast anion transport is demonstrated. A phase‐transfer polymerization process is developed to acquire dense and ordered alignment of quaternary ammonium‐functionalized side chains along the channels within the frameworks. The resultant self‐standing COFs membranes exhibit one of the highest hydroxide conductivities (212 mS cm−1 at 80 °C) among the reported anion exchange membranes. Meanwhile, it is found that shorter, more hydrophilic side chains are favorable for anion conduction. The present work highlights the prospects of all‐organic framework materials as the platform building blocks in designing ion exchange membranes and ion sieving membranes.
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Porous, Crystalline, Covalent Organic Frameworks
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Self-assembly of block copolymers
Mai, Y., & Eisenberg, A. (2012) · Chemical Society Reviews · doi:10.1039/c2cs35115c · Cited by 3,610
The atom, the molecule, and the covalent organic framework
Diercks, C. S., & Yaghi, O. M. (2017) · Science · doi:10.1126/science.aal1585 · Cited by 3,482
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New Insights into Perfluorinated Sulfonic-Acid Ionomers
Kusoglu, A., & Weber, A. Z. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00159 · Cited by 2,432
Anion-exchange membranes in electrochemical energy systems
Varcoe, J. R., Atanassov, P., Dekel, D. R., Herring, A. M., Hickner, M. A., Kohl, P. A., Kucernak, A. R., Mustain, W. E., Nijmeijer, K., Scott, K., et al. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01303d · Cited by 2,051
Covalent organic frameworks: a materials platform for structural and functional designs
Huang, N., Wang, P., & Jiang, D. (2016) · Nature Reviews Materials · doi:10.1038/natrevmats.2016.68 · Cited by 2,017
Covalent organic frameworks for separation applications
Wang, Z., Zhang, S., Chen, Y., Zhang, Z., & Ma, S. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00827f · Cited by 1,470
Self-citationSulfone-containing covalent organic frameworks for photocatalytic hydrogen evolution from water
Wang, X., Chen, L., Chong, S. Y., Little, M. A., Wu, Y., Zhu, W.-H., Clowes, R., Yan, Y., Zwijnenburg, M. A., Sprick, R. S., et al. (2018) · Nature Chemistry · doi:10.1038/s41557-018-0141-5 · Cited by 1,320
Metadata
- Authors
- He, X., Yang, Y., Wu, H., He, G., Xu, Z., Kong, Y., Cao, L., Shi, B., Zhang, Z., Tongsh, C., Jiao, K., Zhu, K., & Jiang, Z.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2020-07-26
- Volume
- 32
- Issue
- 36
- Pages
- e2001284-e2001284
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3044331149
- Cited by
- 253
- References
- 44
- FWCI
- 12.49
- Type
- journal article
- Language
- en
- Open access
- closed
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- He, X., Yang, Y., Wu, H., He, G., Xu, Z., Kong, Y., Cao, L., Shi, B., Zhang, Z., Tongsh, C., Jiao, K., Zhu, K., & Jiang, Z. (2020). De Novo Design of Covalent Organic Framework Membranes toward Ultrafast Anion Transport. Advanced Materials. https://doi.org/10.1002/adma.202001284
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