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Cited by 316

The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.

Over 21% Efficiency Stable 2D Perovskite Solar Cells

Shao, Ming, Bie, Tong, Yang, Lvpeng, Gao, Yerun, Jin, Xing, He, Feng, Zheng, Nan, Yu, Yu, Zhang, Xinliang·2022·Advanced Materials

Abstract

Owing to their insufficient light absorption and charge transport, 2D Ruddlesden–Popper (RP) perovskites show relatively low efficiency. In this work, methylammonium (MA), formamidinum (FA), and FA/MA mixed 2D perovskite solar cells (PSCs) are fabricated. Incorporating FA cations extends the absorption range and enhances the light absorption. Optical spectroscopy shows that FA cations substantially increase the portion of 3D‐like phase to 2D phases, and X‐ray diffraction (XRD) studies reveal that FA‐based 2D perovskite possesses an oblique crystal orientation. Nevertheless, the ultrafast interphase charge transfer results in an extremely long carrier‐diffusion length (≈1.98 µm). Also, chloride additives effectively suppress the yellow δ‐phase formation of pure FA‐based 2D PSCs. As a result, both FA/MA mixed and pure FA‐based 2D PSCs exhibit a greatly enhanced power conversion efficiency (PCE) over 20%. Specifically, the pure FA‐based 2D PSCs achieve a record PCE of 21.07% (certified at 20%), which is the highest efficiency for low‐dimensional PSCs (n ≤ 10) reported to date. Importantly, the FA‐based 2D PSCs retain 97% of their initial efficiency at 85 °C persistent heating after 1500 h. The results unambiguously demonstrate that pure‐FA‐based 2D PSCs are promising for achieving comparable efficiency to 3D perovskites, along with a better device stability.

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Metadata

Authors
Shao, M., Bie, T., Yang, L., Gao, Y., Jin, X., He, F., Zheng, N., Yu, Y., & Zhang, X.
Venue
Advanced Materials
Publisher
Wiley
Published
2021-10-25
Volume
34
Issue
1
Pages
e2107211-e2107211
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W3205342519
Cited by
316
References
34
FWCI
16.42
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Over 21% Efficiency Stable 2D Perovskite Solar Cells. https://app.cochat.ai/papers/10.1002/adma.202107211
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Shao, M., Bie, T., Yang, L., Gao, Y., Jin, X., He, F., Zheng, N., Yu, Y., & Zhang, X. (2022). Over 21% Efficiency Stable 2D Perovskite Solar Cells. Advanced Materials. https://doi.org/10.1002/adma.202107211

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