The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Over 21% Efficiency Stable 2D Perovskite Solar Cells
Abstract
Owing to their insufficient light absorption and charge transport, 2D Ruddlesden–Popper (RP) perovskites show relatively low efficiency. In this work, methylammonium (MA), formamidinum (FA), and FA/MA mixed 2D perovskite solar cells (PSCs) are fabricated. Incorporating FA cations extends the absorption range and enhances the light absorption. Optical spectroscopy shows that FA cations substantially increase the portion of 3D‐like phase to 2D phases, and X‐ray diffraction (XRD) studies reveal that FA‐based 2D perovskite possesses an oblique crystal orientation. Nevertheless, the ultrafast interphase charge transfer results in an extremely long carrier‐diffusion length (≈1.98 µm). Also, chloride additives effectively suppress the yellow δ‐phase formation of pure FA‐based 2D PSCs. As a result, both FA/MA mixed and pure FA‐based 2D PSCs exhibit a greatly enhanced power conversion efficiency (PCE) over 20%. Specifically, the pure FA‐based 2D PSCs achieve a record PCE of 21.07% (certified at 20%), which is the highest efficiency for low‐dimensional PSCs (n ≤ 10) reported to date. Importantly, the FA‐based 2D PSCs retain 97% of their initial efficiency at 85 °C persistent heating after 1500 h. The results unambiguously demonstrate that pure‐FA‐based 2D PSCs are promising for achieving comparable efficiency to 3D perovskites, along with a better device stability.
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Compositional engineering of perovskite materials for high-performance solar cells
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Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
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Self-citationIncorporation of rubidium cations into perovskite solar cells improves photovoltaic performance
Saliba, M., Matsui, T., Domanski, K., Seo, J.-Y., Ummadisingu, A., Zakeeruddin, S. M., Correa-Baena, J.-P., Tress, W. R., Abate, A., Hagfeldt, A., et al. (2016) · Science · doi:10.1126/science.aah5557 · Cited by 3,706
High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells
Tsai, H., Nie, W., Blancon, J.-C., Stoumpos, C. C., Asadpour, R., Harutyunyan, B., Neukirch, A. J., Verduzco, R., Crochet, J. J., Tretiak, S., et al. (2016) · Nature · doi:10.1038/nature18306 · Cited by 3,384
Pseudo-halide anion engineering for α-FAPbI3 perovskite solar cells
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Efficient perovskite solar cells via improved carrier management
Yoo, J. J., Seo, G., Chua, M. R., Park, T. G., Lu, Y., Rotermund, F., Kim, Y.-K., Moon, C. S., Jeon, N. J., Correa-Baena, J.-P., et al. (2021) · Nature · doi:10.1038/s41586-021-03285-w · Cited by 2,934
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A Layered Hybrid Perovskite Solar‐Cell Absorber with Enhanced Moisture Stability
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Metadata
- Authors
- Shao, M., Bie, T., Yang, L., Gao, Y., Jin, X., He, F., Zheng, N., Yu, Y., & Zhang, X.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2021-10-25
- Volume
- 34
- Issue
- 1
- Pages
- e2107211-e2107211
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3205342519
- Cited by
- 316
- References
- 34
- FWCI
- 16.42
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shao, M., Bie, T., Yang, L., Gao, Y., Jin, X., He, F., Zheng, N., Yu, Y., & Zhang, X. (2022). Over 21% Efficiency Stable 2D Perovskite Solar Cells. Advanced Materials. https://doi.org/10.1002/adma.202107211
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