The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
pH, Nanosheet Concentration, and Antioxidant Affect the Oxidation of Ti3C2Tx and Ti2CTx MXene Dispersions
Open accessAbstract
The chemical stability of 2D MXene nanosheets in aqueous dispersions must be maintained to foster their widespread application. MXene nanosheets react with water, which results in the degradation of their 2D structure into oxides and carbon residues. The latter detrimentally restricts the shelf life of MXene dispersions and devices. However, the mechanism of MXene degradation in aqueous environment has yet to be fully understood. In this work, the oxidation kinetics is investigated of Ti 3 C 2 Tx and Ti 2 CTx in aqueous media as a function of initial pH values, ionic strengths, and nanosheet concentrations. The pH value of the dispersion is found to change with time as a result of MXene oxidation. Specifically, MXene oxidation is accelerated in basic media by their reaction with hydroxyl anions. It is also demonstrated that oxidation kinetics are strongly dependent on nanosheet dispersion concentration, in which oxidation is accelerated for lower MXene concentrations. Ionic strength does not strongly affect MXene oxidation. The authors also report that citric acid acts as an effective antioxidant and mitigates the oxidation of both Ti 3 C 2 Tx and Ti 2 CTx MXenes. Reactive molecular dynamic simulations suggest that citric acid associates with the nanosheet edge to hinder the initiation of oxidation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
VMD: visual molecular dynamics
Humphrey, W., Dalke, A., & Schulten, K. (1996) · Journal of Molecular Graphics · doi:10.1016/0263-7855(96)00018-5 · Cited by 66,952
Fast Parallel Algorithms for Short-Range Molecular Dynamics
Plimpton, S. (1995) · Journal of Computational Physics · doi:10.1006/jcph.1995.1039 · Cited by 44,721
Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution
Seh, Z. W., Fredrickson, K. D., Anasori, B., Kibsgaard, J., Strickler, A. L., Lukatskaya, M. R., Gogotsi, Y., Jaramillo, T. F., & Vojvodic, A. (2016) · ACS Energy Letters · doi:10.1021/acsenergylett.6b00247 · Cited by 1,482
Cited by
A Review on MXene Synthesis, Stability, and Photocatalytic Applications
Murali, G., Reddy Modigunta, J. K., Park, Y. H., Lee, J.-H., Rawal, J., Lee, S.-Y., In, I., & Park, S.-J. (2022) · ACS Nano · doi:10.1021/acsnano.2c04750 · Cited by 668
Recent Advances in Oxidation Stable Chemistry of 2D MXenes
Cao, F., Zhang, Y., Wang, H., Khan, K., Tareen, A. K., Qian, W., Zhang, H., & Ågren, H. (2022) · Advanced Materials · doi:10.1002/adma.202107554 · Cited by 648
Metadata
- Authors
- Zhao, X., Vashisth, A., Blivin, J. W., Tan, Z., Holta, D. E., Kotasthane, V., Shah, S. A., Habib, T., Liu, S., Lutkenhaus, J. L., Radovic, M., & Green, M. J.
- Venue
- Advanced Materials Interfaces
- Publisher
- Wiley
- Published
- 2020-08-26
- Volume
- 7
- Issue
- 20
- ISSN
- 2196-7350 (ISSN-L)
- OpenAlex
- W3081564326
- Cited by
- 202
- References
- 3
- FWCI
- 8.58
- Type
- journal article
- Language
- en
- Open access
- bronze
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: pH, Nanosheet Concentration, and Antioxidant Affect the Oxidation of Ti3C2Tx and Ti2CTx MXene Dispersions. https://app.cochat.ai/papers/10.1002/admi.202000845
- The paper
- Zhao, X., Vashisth, A., Blivin, J. W., Tan, Z., Holta, D. E., Kotasthane, V., Shah, S. A., Habib, T., Liu, S., Lutkenhaus, J. L., Radovic, M., & Green, M. J. (2020). pH, Nanosheet Concentration, and Antioxidant Affect the Oxidation of Ti3C2Tx and Ti2CTx MXene Dispersions. Advanced Materials Interfaces. https://doi.org/10.1002/admi.202000845
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
