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Solid Acid Catalysts for Biodiesel Production –‐Towards Sustainable Energy
Abstract
The advantages of biodiesel as an alternative fuel and the problems involved in its manufacturing are outlined. The pros and cons of making biodiesel via fatty acid esterification using solid acid catalysts are examined. The main problem is finding a suitable catalyst that is active, selective, and stable under the process conditions. Various solid acids (zeolites, ion‐exchange resins, and mixed metal oxides) are screened as catalysts in the esterification of dodecanoic acid with 2‐ethylhexanol, 1‐propanol, and methanol at 130–180 °C. The most promising candidate is found to be sulphated zirconia. The catalyst's stability towards thermal decomposition and leaching is tested and the effects of the surface composition and structure on the catalytic activity are discussed.
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Citations
Cited by
Production of liquid biofuels from renewable resources
Nigam, P. S., & Singh, A. (2011) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2010.01.003 · Cited by 2,156
A review on novel processes of biodiesel production from waste cooking oil
Talebian-Kiakalaieh, A., Amin, N. A. S., & Mazaheri, H. (2013) · Applied Energy · doi:10.1016/j.apenergy.2012.11.061 · Cited by 773
Hierarchically Structured Zeolites: From Design to Application
Chen, L.-H., Sun, M.-H., Wang, Z., Yang, W., Xie, Z., & Su, B.-L. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00016 · Cited by 724
Catalytic Applications in the Production of Biodiesel from Vegetable Oils
Sivasamy, A., Cheah, K. Y., Fornasiero, P., Kemausuor, F., Zinoviev, S., & Miertus, S. (2009) · ChemSusChem · doi:10.1002/cssc.200800253 · Cited by 339
Dong, T., Gao, D., Miao, C., Yu, X., Degan, C., Garcia-Pérez, M., Rasco, B., Sablani, S. S., & Chen, S. (2015) · Energy Conversion and Management · doi:10.1016/j.enconman.2015.06.072 · Cited by 125
Metadata
- Authors
- Kiss, A. A., Dimian, A. C., & Rothenberg, G.
- Venue
- Advanced Synthesis & Catalysis
- Publisher
- Wiley
- Published
- 2006-01
- Volume
- 348
- Issue
- 1-2
- Pages
- 75-81
- ISSN
- 1615-4150 (ISSN-L)
- 1615-4169
- OpenAlex
- W2101537134
- Cited by
- 578
- References
- 0
- FWCI
- 19.26
- Type
- journal article
- Language
- en
- Open access
- closed
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- Kiss, A. A., Dimian, A. C., & Rothenberg, G. (2006). Solid Acid Catalysts for Biodiesel Production –‐Towards Sustainable Energy. Advanced Synthesis & Catalysis. https://doi.org/10.1002/adsc.200505160
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
